Ambient-Dried Silica Aerogel Powders Derived from Coal Gangue by Using One-Pot Method.

In this paper, we report a new and convenient method for the synthesis of insulating aerogel by recycling solid waste coal gangue, which can reduce the industrial production cost of silica aerogels and realize high value-added utilization of solid waste. Sodium silicate was prepared from a cheap industrial waste coal gangue as the precursor for silica aerogels, which was used for silica wet gel preparation by a one pot method; this method of solvent exchange/surface modification was carried out quickly by mechanical stirring process, and the wet gels derived from coal gangue were dried under ambient pressure condition. A high surface area (748 m/g) nanostructured aerogel with a 3D open porous microstructure was synthesized, which exhibits a low density (0.18 g/cm) and a superior thermal insulation performance (~0.033 W·m·K). More significantly, the synthetic yield of silica aerogel powder by recycling coal gangue can reach 92%.