• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

基于2-碘对苯二甲酸和1,2-双(4-吡啶基)乙烷的锌(II)和钴(II)三维配位聚合物：结构与吸附性能

Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties.

作者信息

Zaguzin Alexander S, Sukhikh Taisiya S, Sakhapov Ilyas F, Fedin Vladimir P, Sokolov Maxim N, Adonin Sergey A

机构信息

South Ural State University, Lenina St. 76, 454080 Chelyabinsk, Russia.

Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentieva St. 3, 630090 Novosibirsk, Russia.

出版信息

Molecules. 2022 Feb 15;27(4):1305. doi: 10.3390/molecules27041305.

DOI:10.3390/molecules27041305
PMID:35209092
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8876937/
Abstract

Metal-organic frameworks [M(2-I-bdc)bpe] (M = Zn(II) (), Co(II) (), 2-I-bdc = 2-iodoterephtalic acid, and bpe = 1,2-bis(4-pyridyl)ethane) were prepared and characterized by X-ray diffractometry. Both compounds retain their 3D structure after the removal of guest DMF molecules. Selectivity of sorption of different organic substrates from the gas phase was investigated for both complexes.

摘要

制备了金属有机框架[M(2-I-bdc)bpe]（M = Zn(II)（），Co(II)（），2-I-bdc = 2-碘对苯二甲酸，bpe = 1,2-双(4-吡啶基)乙烷），并通过X射线衍射法对其进行了表征。去除客体N,N-二甲基甲酰胺（DMF）分子后，两种化合物均保留其三维结构。研究了两种配合物从气相中吸附不同有机底物的选择性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/ee829fd3684b/molecules-27-01305-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/01efe3a4c108/molecules-27-01305-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/c3c3550a0888/molecules-27-01305-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/3861aeab0356/molecules-27-01305-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/58eb473017db/molecules-27-01305-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/ee829fd3684b/molecules-27-01305-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/01efe3a4c108/molecules-27-01305-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/c3c3550a0888/molecules-27-01305-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/3861aeab0356/molecules-27-01305-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/58eb473017db/molecules-27-01305-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/72d1/8876937/ee829fd3684b/molecules-27-01305-g005.jpg

相似文献

1
Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties.基于2-碘对苯二甲酸和1,2-双(4-吡啶基)乙烷的锌(II)和钴(II)三维配位聚合物：结构与吸附性能
Molecules. 2022 Feb 15;27(4):1305. doi: 10.3390/molecules27041305.
2
Modular, homochiral, porous coordination polymers: rational design, enantioselective guest exchange sorption and ab initio calculations of host-guest interactions.模块化、手性、多孔配位聚合物：合理设计、对映选择性客体交换吸附及主客体相互作用的从头算计算。
Chemistry. 2010 Sep 10;16(34):10348-56. doi: 10.1002/chem.201000522.
3
Cd(II) and Zn(II) coordination polymers assembled from benzoyltrifluoroacetone and 1,2-bis(4-pyridyl)ethane ancillary ligands.由苯甲酰三氟丙酮和1,2 - 双（4 - 吡啶基）乙烷辅助配体组装而成的镉（II）和锌（II）配位聚合物。
Acta Chim Slov. 2013;60(2):328-34.
4
Four Mixed-Ligand Zn(II) Three-Dimensional Metal-Organic Frameworks: Synthesis, Structural Diversity, and Photoluminescent Property.四种混合配体锌（II）三维金属有机框架：合成、结构多样性及光致发光性质
Polymers (Basel). 2017 Nov 25;9(12):644. doi: 10.3390/polym9120644.
5
Structural Diversity and Carbon Dioxide Sorption Selectivity of Zinc(II) Metal-Organic Frameworks Based on Bis(1,2,4-triazol-1-yl)methane and Terephthalic Acid.基于双（1,2,4-三唑-1-基）甲烷和对苯二甲酸的锌（II）金属有机框架的结构多样性和二氧化碳吸附选择性
Molecules. 2022 Oct 1;27(19):6481. doi: 10.3390/molecules27196481.
6
From 1D to 2D Cd(II) and Zn(II) Coordination Networks by Replacing Monocarboxylate with Dicarboxylates in Partnership with Azine Ligands: Synthesis, Crystal Structures, Inclusion, and Emission Properties.从 1D 到 2D 的 Cd(II)和 Zn(II)配位网络，通过用二羧酸取代一元羧酸与嗪配体协同作用：合成、晶体结构、包合和发光性质。
Molecules. 2020 Nov 29;25(23):5616. doi: 10.3390/molecules25235616.
7
Flexible porous coordination polymers constructed from 1,2-bis(4-pyridyl)hydrazine via solvothermal in situ reduction of 4,4'-azopyridine.通过溶剂热原位还原 4,4'-联吡啶，由 1,2-双(4-吡啶基)肼构建的柔性多孔配位聚合物。
Dalton Trans. 2011 Sep 14;40(34):8549-54. doi: 10.1039/c1dt10682a. Epub 2011 Jul 26.
8
Cd(ii) coordination polymers constructed from bis(pyridyl) ligands with an asymmetric spacer in chelating mode and diverse organic dicarboxylates: syntheses, structural evolutions and properties.由具有不对称间隔基的双吡啶配体以螯合模式与多种有机二羧酸酯构建的Cd(ii)配位聚合物：合成、结构演变及性质
Dalton Trans. 2019 Jun 14;48(22):7589-7601. doi: 10.1039/c9dt00840c. Epub 2019 May 8.
9
Effect of flexible bis-pyridyl-bis-amide ligands and dicarboxylates on the assembly and properties of multifunctional Cu(II) metal-organic coordination polymers.柔性双吡啶双酰胺配体和二羧酸对多功能 Cu(II) 金属有机配位聚合物的组装和性能的影响。
Dalton Trans. 2013 Jun 21;42(23):8375-86. doi: 10.1039/c3dt50202c. Epub 2013 Apr 26.
10
Syntheses and crystal structures of a series of coordination polymers constructed from C2-symmetric ligand 1,3-adamantanedicarboxylic acid.一系列由 C2 对称配体 1,3-金刚烷二甲酸构建的配位聚合物的合成及晶体结构。
Chem Asian J. 2010 Jul 5;5(7):1611-9. doi: 10.1002/asia.200900751.

引用本文的文献

1
Determining Factors to Understand the External Quantum Efficiency Values: Study Carried Out with Copper(I)-I and 1,2-Bis(4-pyridyl)ethane Coordination Polymers as Downshifters in Photovoltaic Modules.理解外量子效率值的决定因素：以碘化亚铜与1,2 - 双（4 - 吡啶基）乙烷配位聚合物作为光伏组件中的降频器进行的研究
Inorg Chem. 2024 Mar 11;63(10):4646-4656. doi: 10.1021/acs.inorgchem.3c04232. Epub 2024 Mar 1.
2
Zinc(II) Carboxylate Coordination Polymers with Versatile Applications.锌(II)羧酸配合物的多功能应用。
Molecules. 2023 Jan 23;28(3):1132. doi: 10.3390/molecules28031132.

本文引用的文献

1
Fabricated Metal-Organic Frameworks (MOFs) as luminescent and electrochemical biosensors for cancer biomarkers detection.用于癌症生物标志物检测的发光和电化学生物传感器的合成金属有机框架（MOFs）。
Biosens Bioelectron. 2022 Feb 1;197:113738. doi: 10.1016/j.bios.2021.113738. Epub 2021 Oct 29.
2
Harnessing Shape Complementarity for Upgraded Cyclohexane Purification through Adaptive Bottlenecked Pores in an Imidazole-Containing MOF.通过咪唑功能化 MOF 中的自适应瓶颈孔实现环己烷的升级纯化。
Angew Chem Int Ed Engl. 2021 Oct 25;60(44):23590-23595. doi: 10.1002/anie.202109964. Epub 2021 Oct 1.
3
The Z-scheme NH-UiO-66/PTCDA composite for enhanced photocatalytic Cr(VI) reduction under low-power LED visible light.
Z 型 NH-UiO-66/PTCDA 复合材料在低功率 LED 可见光下增强光催化 Cr(VI)还原。
Chemosphere. 2021 Oct;280:130734. doi: 10.1016/j.chemosphere.2021.130734. Epub 2021 May 4.
4
Separation and Purification of Hydrocarbons with Porous Materials.用多孔材料分离和提纯碳氢化合物。
Angew Chem Int Ed Engl. 2021 Aug 23;60(35):18930-18949. doi: 10.1002/anie.202104318. Epub 2021 May 6.
5
Exceptionally effective benzene/cyclohexane separation using a nitro-decorated metal-organic framework.使用硝基修饰的金属有机框架实现高效的苯/环己烷分离。
Chem Commun (Camb). 2020 Jul 23;56(59):8241-8244. doi: 10.1039/d0cc03227a.
6
Hexaiododiplatinate(ii) as a useful supramolecular synthon for halogen bond involving crystal engineering.六碘合二价铂(ii)作为涉及卤键的超分子构筑基元在晶体工程中的应用。
Dalton Trans. 2020 Jan 2;49(2):356-367. doi: 10.1039/c9dt04221k.
7
Iodine Adsorption in a Redox-Active Metal-Organic Framework: Electrical Conductivity Induced by Host-Guest Charge-Transfer.氧化还原活性金属有机骨架中的碘吸附：主体-客体电荷转移引起的电导率。
Inorg Chem. 2019 Oct 21;58(20):14145-14150. doi: 10.1021/acs.inorgchem.9b02176. Epub 2019 Sep 30.
8
Halogen bonding in UiO-66 frameworks promotes superior chemical warfare agent simulant degradation.UiO-66 骨架中的卤键促进了优越的化学战剂模拟物的降解。
Chem Commun (Camb). 2019 Mar 19;55(24):3481-3484. doi: 10.1039/c9cc00642g.
9
Dramatically Enhanced Solubility of Halide-Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅Complex Halogen Bonding.含卤有机金属物种在二碘甲烷中溶解度的显著提高：溶剂⋅⋅⋅复合卤素键的作用
Angew Chem Int Ed Engl. 2018 Sep 24;57(39):12785-12789. doi: 10.1002/anie.201807642. Epub 2018 Aug 29.
10
Exploring the Effect of Ligand-Originated MOF Isomerism and Methoxy Group Functionalization on Selective Acetylene/Methane and Carbon Dioxide/Methane Adsorption Properties in Two NbO-Type MOFs.探究配体起源的 MOF 同构和甲氧基官能化对两种 NbO 型 MOF 中乙炔/甲烷和二氧化碳/甲烷吸附选择性的影响。
ACS Appl Mater Interfaces. 2018 Jun 20;10(24):20559-20568. doi: 10.1021/acsami.8b05216. Epub 2018 Jun 11.