基于2-碘对苯二甲酸和1,2-双(4-吡啶基)乙烷的锌(II)和钴(II)三维配位聚合物：结构与吸附性能
Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties.
作者信息
Zaguzin Alexander S, Sukhikh Taisiya S, Sakhapov Ilyas F, Fedin Vladimir P, Sokolov Maxim N, Adonin Sergey A
机构信息
South Ural State University, Lenina St. 76, 454080 Chelyabinsk, Russia.
Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentieva St. 3, 630090 Novosibirsk, Russia.
出版信息
Molecules. 2022 Feb 15;27(4):1305. doi: 10.3390/molecules27041305.
Metal-organic frameworks [M(2-I-bdc)bpe] (M = Zn(II) (), Co(II) (), 2-I-bdc = 2-iodoterephtalic acid, and bpe = 1,2-bis(4-pyridyl)ethane) were prepared and characterized by X-ray diffractometry. Both compounds retain their 3D structure after the removal of guest DMF molecules. Selectivity of sorption of different organic substrates from the gas phase was investigated for both complexes.
制备了金属有机框架[M(2-I-bdc)bpe]（M = Zn(II)（），Co(II)（），2-I-bdc = 2-碘对苯二甲酸，bpe = 1,2-双(4-吡啶基)乙烷），并通过X射线衍射法对其进行了表征。去除客体N,N-二甲基甲酰胺（DMF）分子后，两种化合物均保留其三维结构。研究了两种配合物从气相中吸附不同有机底物的选择性。
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