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**绿色合成**:**植物**提取液**超顺磁性氧化铁纳米粒子**及其在**去除**农业土壤中重金属的应用。

Green Synthesis of Superparamagnetic Iron Oxide Nanoparticles with Extract and Their Application in the Removal of Heavy Metals from Agricultural Soil.

机构信息

Facultad de Ingeniería, Ingeniería Ambiental, Universidad Privada del Norte, Trujillo 13011, Peru.

Dirección de Investigación, Innovación & Responsabilidad Social, Universidad Privada del Norte, Trujillo 13011, Peru.

出版信息

Molecules. 2022 Feb 17;27(4):1367. doi: 10.3390/molecules27041367.

Abstract

The green synthesis of metal oxide nanoparticles is presented as an excellent sustainable alternative for achieving nanostructures, with potential applications. This research provides important information regarding the influence of the type of solvent used in extracting organic reducing agents from on the FeO NPs green synthesis protocol. A broad approach to characterization is presented, where UV-vis spectrophotometry suggests the presence of this type of nanoparticulate material. Likewise, the reduction mechanism was evaluated by FT-IR and the magnetic properties were evaluated by PPSM. In addition, characterizations were linked via elemental analysis (EDX), crystallographic characterization (XRD), electron microscopy (SEM/STEM), and Z potential to evaluate colloidal stability. The results show the influence of the type of solvent used for the extraction of organic reducing agents from , and the effect on the synthesis of FeO NPs. In addition, the nanostructure material obtained showed excellent efficiency in the remediation of agricultural soil, eliminating metals such as Cr-VI, Cd, and, to a lesser extent, Pb.

摘要

金属氧化物纳米粒子的绿色合成被提出作为实现纳米结构的一种极好的可持续替代方法,具有潜在的应用。本研究提供了关于在从 中提取有机还原剂时所使用的溶剂类型对 FeO NPs 绿色合成方案的影响的重要信息。提出了一种广泛的表征方法,其中紫外-可见分光光度法表明存在这种类型的纳米颗粒材料。同样,通过 FT-IR 评估了还原机制,通过 PPSM 评估了磁性。此外,通过元素分析(EDX)、晶体学表征(XRD)、电子显微镜(SEM/STEM)和 Z 电位进行了表征,以评估胶体稳定性。结果表明了用于从 中提取有机还原剂的溶剂类型的影响,以及对 FeO NPs 合成的影响。此外,所获得的纳米结构材料在修复农业土壤方面表现出优异的效率,消除了 Cr-VI、Cd 和在较小程度上的 Pb 等金属。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49ee/8880537/fad904f1a587/molecules-27-01367-g001.jpg

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