Recent Advances in Environmentally Friendly and Green Degumming Processes of Silk for Textile and Non-Textile Applications.

Silk has been widely used not only in the textile field but also in non-textile applications, which is composed of inner fibrous protein, named fibroin, and outer global protein, named sericin. Due to big differences, such as appearance, solubility, amino acid composition and amount of reactive groups, silk fibroin and sericin usually need to be separated before further process. The residual sericin may influence the molecular weight, structure, morphology and properties of silk fibroin, so that degumming of silk is important and necessary, not only in textile field but also in non-textile applications. Traditional textile degumming processes, including soap, alkali or both, could bring such problems as environmental damage, heavy use of water and energy, and damage to silk fibroin. Therefore, this review aims to present a systematic work on environmentally friendly and green degumming processes of raw silk, including art of green degumming process, quantitative and qualitative evaluation, influence of degumming on molecular weight, structure, morphology and properties of silk. It is anticipated that rational selection and design of environmentally friendly and green degumming process is quite important and meaningful, not only for textile application but also for non-textile application.