基于对苯二酚杯[6]芳烃的膦金（I）穴状配体

Giovanardi Gabriele, Secchi Andrea, Arduini Arturo, Cera Gianpiero

Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy.

Beilstein J Org Chem. 2022 Feb 10;18:190-196. doi: 10.3762/bjoc.18.21. eCollection 2022.

We report the synthesis and characterization, in low polarity solvents, of a novel class of diametric phosphine gold(I) cavitands characterized by a geometry. Preliminary catalytic studies were performed on a model cycloisomerization of 1,6-enynes as a function of the relative orientation of the bonded gold(I) nuclei with respect to the macrocyclic cavity.

我们报道了一类新型的直径膦金（I）穴状配体在低极性溶剂中的合成与表征，其具有特定几何结构。针对1,6-烯炔的模型环异构化反应，作为键合金（I）核相对于大环腔的相对取向的函数进行了初步催化研究。