Two-Dimensional Weak Antilocalization Signatures Due to Quantum Coherent Transport in Nanocrystalline SnTe.

Nanostructured topological crystalline insulators (TCIs) in the presence of exotic surface states with spin momentum locking reported in individual nanostructures are predicted to hold a great promise for spintronics and quantum computing applications. However, practical application demands a strategy with large-scale production and integration for device applications. In this work, we demonstrate through prominent signatures of weak antilocalization (WAL), arising predominantly from destructive quantum interference on robust surface states, that a correlated TCI phase is possible in the nanobulk assembly of carefully nanostructured quasi-two-dimensional SnTe (edge-to-edge length ∼ 382 nm) synthesized by a simple, rapid, and scalable microwave-assisted solvothermal method. Hikami-Larkin-Nagaoka analysis (), as well as the temperature dependence of resistivity, illustrates an interplay of both conductions from 2D channels and 3D EEI effects as the precursor for the observed WAL at low temperatures (2-6 K). Interestingly, the enhanced thermoelectric power of the sample of ∼45 μV/K, with a p-type carrier concentration of ∼10/cm at 300 K, makes this SnTe nanocrystalline assembly more attractive as a multifunctional material for large-scale technological applications.