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用于高效电磁干扰屏蔽的三维打印碳纳米管/聚乳酸复合材料

Three-Dimensional-Printed Carbon Nanotube/Polylactic Acid Composite for Efficient Electromagnetic Interference Shielding.

作者信息

Xu Zhenzhen, Dou Tiantian, Wang Yazhou, Zuo Hongmei, Chen Xinyu, Zhang Mingchun, Zou Lihua

机构信息

School of Textile and Garment, Anhui Polytechnic University, Wuhu 241000, China.

Anhui Province International Cooperation Research Center of Textile Structure Composite Materials, Anhui Polytechnic University, Wuhu 241000, China.

出版信息

Polymers (Basel). 2023 Jul 18;15(14):3080. doi: 10.3390/polym15143080.

Abstract

High-performance electromagnetic interference (EMI) shielding materials with ultralow density and environment-friendly properties are greatly demanded to address electromagnetic radiation pollution. Herein, carbon nanotube/polylactic acid (CNT/PLA) materials with different CNT contents, which exhibit characteristics of light weight, environmental protection and good chemical stability, are fabricated using 3D printing technology, where CNTs are evenly distributed and bind well with PLA. The performances of 3D-printed CNT/PLA composites are improved compared to pure 3D-printed PLA composites, which include mechanical properties, conductive behaviors and electromagnetic interference (EMI) shielding. The EMI shielding effectiveness (SE) of CNT/PLA composites could be improved when the content of CNTs increase. When it reaches 15 wt%, the EMI SE of 3D-printed CNT/PLA composites could get up to 47.1 dB, which shields 99.998% of electromagnetic energy. Meanwhile, the EMI shielding mechanism of 3D-printed CNT/PLA composites is mainly of absorption loss, and it generally accounts for more than 80% of the total shielding loss. These excellent comprehensive performances endow a 3D-printed CNT/PLA composite with great potential for use in industrial and aerospace areas.

摘要

为应对电磁辐射污染,人们迫切需要具有超低密度和环保特性的高性能电磁干扰(EMI)屏蔽材料。在此,采用3D打印技术制备了具有不同碳纳米管(CNT)含量的碳纳米管/聚乳酸(CNT/PLA)材料,该材料具有重量轻、环保和良好化学稳定性的特点,其中CNT均匀分布且与PLA结合良好。与纯3D打印PLA复合材料相比,3D打印CNT/PLA复合材料的性能得到了改善,包括机械性能、导电行为和电磁干扰(EMI)屏蔽性能。当CNT含量增加时,CNT/PLA复合材料的EMI屏蔽效能(SE)会提高。当含量达到15 wt%时,3D打印CNT/PLA复合材料的EMI SE可达47.1 dB,可屏蔽99.998%的电磁能量。同时,3D打印CNT/PLA复合材料的EMI屏蔽机制主要是吸收损耗,通常占总屏蔽损耗的80%以上。这些优异的综合性能赋予了3D打印CNT/PLA复合材料在工业和航空航天领域的巨大应用潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/608e/10385445/5d8a8fe3ba36/polymers-15-03080-g001.jpg

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