Zhang Lunyong, Huang Yongjiang, Wu Ming, Xu Chao, Ning Zhiliang, Cao Fuyang, Sun Jianfei
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China.
National Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, Harbin 150001, China.
Materials (Basel). 2022 Feb 24;15(5):1686. doi: 10.3390/ma15051686.
Developing light structure materials that work stably at elevated temperatures is a long-standing challenge for many application fields, particularly in the development of aerospace equipment. Zn/Cd alloying elements were prospected to improve the stability of the lightest Mg-Li based alloys; however, little is known about the intermediate-temperature mechanical properties of such alloys. The present work investigated the tensile behaviors of a cold-rolled Mg-Li-Al-Cd-Zn alloy in a temperature range of 30-150 °C. The results indicate that the alloy can host a tensile strength σ of 108121 MPa, a yield strength σ of 97109 MPa and elongation of 14-15 % at 150 °C, dependent on the tensile direction. The mechanical properties intensively are modulated by temperature through the competition between work hardening and softening. Work hardening due to dislocation blocking by the precipitated MgLiX phase dominated the deformation at low temperatures, while softening that resulted from dynamic recrystallization was the main effect at high temperatures. Correspondingly, a quasi-cleavage mechanism dominated the fracture at temperatures near room temperature, and microvoid coalescence worked at high temperatures above 100 °C. Our results offer a new experimental understanding of the elevated-temperature mechanical behaviors of Mg-Li alloys and will advance the development of new light magnesium alloys with high stability.
开发在高温下稳定工作的轻质结构材料对许多应用领域来说是一项长期挑战,尤其是在航空航天设备的开发中。锌/镉合金元素有望提高最轻的镁锂基合金的稳定性;然而,对于这类合金的中温力学性能却知之甚少。目前的工作研究了一种冷轧镁锂铝镉锌合金在30-150°C温度范围内的拉伸行为。结果表明,该合金在150°C时的抗拉强度σ为108121MPa,屈服强度σ为97109MPa,伸长率为14-15%,具体取决于拉伸方向。力学性能通过加工硬化和软化之间的竞争而强烈地受温度调制。低温下,由析出的MgLiX相阻碍位错导致的加工硬化主导了变形,而高温下动态再结晶引起的软化是主要影响因素。相应地,在接近室温的温度下,准解理机制主导断裂,而在100°C以上的高温下,微孔聚集起作用。我们的结果为镁锂合金的高温力学行为提供了新的实验认识,并将推动具有高稳定性的新型轻质镁合金的开发。