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具有抗菌性能的二氧化钛改性磁性纳米颗粒(FeO)

TiO-Modified Magnetic Nanoparticles (FeO) with Antibacterial Properties.

作者信息

Wojciechowska Agnieszka, Markowska-Szczupak Agata, Lendzion-Bieluń Zofia

机构信息

Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, Aleja Piastów 42, 71-065 Szczecin, Poland.

出版信息

Materials (Basel). 2022 Mar 2;15(5):1863. doi: 10.3390/ma15051863.

Abstract

This paper presents the synthesis and characteristics of FeO/C/TiO hybrid magnetic nanomaterials with antibacterial properties. The materials used were obtained using a microwave-assisted two-stage precipitation method. In the first stage, magnetite nanoparticles (FeO) were prepared with the precipitation method, during which an additional glucose layer was placed on them. Next, the surface of FeO nanoparticles was covered by TiO. It was observed that the addition of carbon and titanium dioxide caused a decrease in the average size of magnetite crystallites from 15.6 to 9.2 nm. Materials with varying contents of anatase phase were obtained. They were characterized in terms of phase composition, crystallite size, specific surface area, surface charge and the kinds of function groups on the surface. The results show a successful method of synthesizing hybrid magnetic nanoparticles, stable in a solution, with antibacterial properties under direct solar light irradiation. Compared to classical materials based on TiO and used for water disinfection, the obtained photocatalytic nanomaterials have magnetic properties. Owing to this fact, they can be easily removed from water once their activity under direct irradiance in a given process has completed.

摘要

本文介绍了具有抗菌性能的FeO/C/TiO混合磁性纳米材料的合成及特性。所用材料通过微波辅助两步沉淀法获得。在第一阶段,采用沉淀法制备磁铁矿纳米颗粒(FeO),在此过程中在其表面附加了一层葡萄糖。接下来,FeO纳米颗粒的表面被TiO覆盖。观察到碳和二氧化钛的加入使磁铁矿微晶的平均尺寸从15.6纳米减小到9.2纳米。获得了具有不同锐钛矿相含量的材料。对它们进行了相组成、微晶尺寸、比表面积、表面电荷以及表面官能团种类等方面的表征。结果表明,成功合成了在溶液中稳定、在太阳光直接照射下具有抗菌性能的混合磁性纳米颗粒。与用于水消毒的基于TiO的传统材料相比,所制备的光催化纳米材料具有磁性。因此,一旦它们在给定过程中的直接辐照下的活性完成,就可以很容易地从水中去除。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3cd5/8911625/d1b96003f59e/materials-15-01863-g001.jpg

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