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具有可控弹性的热拉伸高导电纤维

Thermally Drawn Highly Conductive Fibers with Controlled Elasticity.

作者信息

Marion Juliette S, Gupta Nikhil, Cheung Henry, Monir Kirmina, Anikeeva Polina, Fink Yoel

机构信息

Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA.

Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA, 02139, USA.

出版信息

Adv Mater. 2022 May;34(19):e2201081. doi: 10.1002/adma.202201081. Epub 2022 Apr 5.

Abstract

Electronic fabrics necessitate both electrical conductivity and, like any textile, elastic recovery. Achieving both requirements on the scale of a single fiber remains an unmet need. Here, two approaches for achieving conductive fibers (10 S m ) reaching 50% elongation while maintaining minimal change in resistance (<0.5%) in embedded metallic electrodes are introduced. The first approach involves inducing a buckling instability in a metal microwire within a cavity of a thermally drawn elastomer fiber. The second approach relies on twisting an elastomer fiber to yield helical metal electrodes embedded in a stretchable yarn. The scalability of both approaches is illustrated in apparatuses for continuous buckling and twisting that yield tens of meters of elastic conducting fibers. Through experimental and analytical methods, it is elucidated how geometric parameters, such as buckling pre-strain and helical angle, as well as materials choice, control not only the fiber's elasticity but also its Young's modulus. Links between mechanical and electrical properties are exposed. The resulting fibers are used to construct elastic fabrics that contain diodes, by weaving and knitting, thus demonstrating the scalable fabrication of conformable and stretchable antennas that support optical data transmission.

摘要

电子织物既需要导电性,又像任何纺织品一样需要弹性回复。在单根纤维的尺度上同时满足这两个要求仍然是一个未被满足的需求。在此,介绍了两种实现导电纤维(10 S/m)的方法,这种纤维在嵌入式金属电极中伸长50%时电阻变化最小(<0.5%)。第一种方法是在热拉伸弹性体纤维的空腔内的金属微丝中诱导屈曲不稳定性。第二种方法是将弹性体纤维捻成螺旋状,使金属电极嵌入可拉伸纱线中。两种方法的可扩展性在用于连续屈曲和捻合的设备中得到了体现,这些设备可生产出数十米的弹性导电纤维。通过实验和分析方法,阐明了诸如屈曲预应变和螺旋角等几何参数以及材料选择如何不仅控制纤维的弹性,还控制其杨氏模量。揭示了机械性能和电学性能之间的联系。通过编织和针织,将所得纤维用于构建包含二极管的弹性织物,从而展示了可扩展制造支持光数据传输的贴合且可拉伸天线的能力。

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