Department of Organic Chemistry, Faculty of Chemistry, University of Science, Ho Chi Minh City, Vietnam.
Vietnam National University, Ho Chi Minh City, Vietnam.
ChemSusChem. 2022 Jul 7;15(13):e202200220. doi: 10.1002/cssc.202200220. Epub 2022 Apr 22.
The conversion of biomass into a great variety of valuable chemicals, polymers, and fuels gives a sustainable alternative for the insufficiency of non-renewable fossil fuel resources and reduces environmental pollution. 5-Hydroxymethylfurfural (HMF), converted from sustainable carbohydrates, is a significant building block chemical, and the selective oxidation of HMF into 2,5-diformylfuran (DFF) presents an ongoing challenge. DFF is a versatile platform molecule derived from biomass and has promising application in pharmaceuticals and polymers. This Review provides an overview of the latest developments of efficient catalytic systems for the sustainable conversion of HMF to DFF.
将生物质转化为各种有价值的化学品、聚合物和燃料，为不可再生化石燃料资源的不足提供了一种可持续的替代方案，并减少了环境污染。5-羟甲基糠醛（HMF）可由可持续碳水化合物转化而来，是一种重要的结构单元化学品，而选择性氧化 HMF 为 2,5-二醛基呋喃（DFF）则是一个持续存在的挑战。DFF 是一种源自生物质的多功能平台分子，在药物和聚合物中有广阔的应用前景。本综述概述了高效催化体系将 HMF 可持续转化为 DFF 的最新进展。
