Palos Roberto, Gutiérrez Alazne, Vela Francisco J, Olazar Martin, Arandes José M, Bilbao Javier
Department of Chemical Engineering, University of the Basque Country UPV/EHU, PO Box 644, 48080 Bilbao, Spain.
Energy Fuels. 2021 Mar 4;35(5):3529-3557. doi: 10.1021/acs.energyfuels.0c03918. Epub 2021 Feb 9.
This review collects a wide range of initiatives and results that expose the potential of the refineries to be converted into waste refineries. Thus, they will use their current units for the valorization of consumer society wastes (waste plastics and end-of-life tires in particular) that are manufactured with petroleum derivatives. The capacity, technological development, and versatility of fluid catalytic cracking (FCC) and hydroprocessing units make them appropriate for achieving this goal. Polyolefinic plastics (polyethylene and polypropylene), the waxes obtained in their fast pyrolysis, and the tire pyrolysis oils can be cofed together with the current streams of the industrial units. Conventional refineries have the opportunity of operating as waste refineries cofeeding these alternative feeds and tailoring the properties of the fuels and raw materials produced to be adapted to commercial requirements within the oil economy frame. This strategy will contribute in a centralized and rational way to the recycling of the consumer society wastes on a large scale. Furthermore, the use of already existing and, especially, depreciated units for the production of fuels and raw materials (such as light olefins and aromatics) promotes the economy of the recycling process.
本综述收集了一系列举措和成果,这些举措和成果揭示了炼油厂转变为废物炼油厂的潜力。因此,它们将利用其现有装置对由石油衍生物制造的消费社会废物(特别是废塑料和废旧轮胎)进行增值利用。流化催化裂化(FCC)装置和加氢处理装置的能力、技术发展和通用性使其适合实现这一目标。聚烯烃塑料(聚乙烯和聚丙烯)、其快速热解过程中获得的蜡以及轮胎热解油可以与工业装置的现有物流一起共进料。传统炼油厂有机会作为废物炼油厂运行,共进料这些替代原料,并调整所生产燃料和原料的性质,以适应石油经济框架内的商业需求。这一战略将以集中和合理的方式大规模促进消费社会废物的回收利用。此外,利用现有且特别是已折旧的装置来生产燃料和原料(如轻质烯烃和芳烃)可提高回收过程的经济性。