铈（III）/光辅助下由羧酸和异氰酸酯合成酰胺
Ce(III)/Photoassisted Synthesis of Amides from Carboxylic Acids and Isocyanates.
作者信息
Li Hao-Cong, Li Guan-Nan, Sun Kai, Chen Xiao-Lan, Jiang Ming-Xuan, Qu Ling-Bo, Yu Bing
机构信息
Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, China.
出版信息
Org Lett. 2022 Apr 1;24(12):2431-2435. doi: 10.1021/acs.orglett.2c00699. Epub 2022 Mar 21.
PMID:35311287
Abstract
The Ce(III)-photocatalyzed synthesis of amides from carboxylic acids and aryl isocyanates was developed. The reaction includes the formation of alkyl radicals from carboxylic acids followed by radical addition to the electron-deficient carbon of isocyanate.
摘要
开发了铈（III）光催化从羧酸和芳基异氰酸酯合成酰胺的方法。该反应包括从羧酸形成烷基自由基，然后自由基加成到异氰酸酯的缺电子碳上。
Zotero 插件