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基于事件相机在实时速度分辨动力学中的应用。

Application of an Event-Based Camera for Real-Time Velocity Resolved Kinetics.

作者信息

Golibrzuch Kai, Schwabe Sven, Zhong Tianli, Papendorf Kim, Wodtke Alec M

机构信息

Max-Planck-Institute for Multidisciplinary Sciences, Am Fassberg 11, D-37077 Goettingen, Germany.

Institute for Physical Chemistry, Georg-August-University Goettingen, Tammannstrasse 6, D- 37077 Goettingen, Germany.

出版信息

J Phys Chem A. 2022 Apr 7;126(13):2142-2148. doi: 10.1021/acs.jpca.2c00806. Epub 2022 Mar 23.

DOI:10.1021/acs.jpca.2c00806
PMID:35319892
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8996233/
Abstract

We describe here the application of an inexpensive event-based/neuromorphic camera in an ion imaging experiment operated at 1 kHz detection rate to study real-time velocity-resolved kinetics of thermal desorption. Such measurements involve a single gas pulse to initiate a time-dependent desorption process and a high repetition rate laser, where each pulse of the laser is used to produce an ion image. The sequence of ion images allows the time dependence of the desorption flux to be followed in real time. In previous work where a conventional framing camera was used, the large number of megapixel-sized images required data transfer and storage rates of up to 16 GB/s. This necessitated a large onboard memory that was quickly filled and limited continuous measurement to only a few seconds. Read-out of the memory became the bottleneck to the rate of data acquisition. We show here that since most pixels in each ion image contain no data, the data rate can be dramatically reduced by using an event-based/neuromorphic camera. The data stream is thus reduced to the intensity and location information on the pixels that are lit up by each ion event together with a time-stamp indicating the arrival time of an ion at the detector. This dramatically increases the duty cycle of the method and provides insights for the execution of other high rep-rate ion imaging experiments.

摘要

我们在此描述了一种廉价的基于事件/神经形态相机在离子成像实验中的应用,该实验以1 kHz的检测速率运行,用于研究热脱附的实时速度分辨动力学。此类测量涉及单个气体脉冲以启动随时间变化的脱附过程以及高重复率激光,其中激光的每个脉冲用于生成离子图像。离子图像序列允许实时跟踪脱附通量的时间依赖性。在之前使用传统帧相机的工作中,大量百万像素大小的图像需要高达16 GB/s的数据传输和存储速率。这就需要一个大容量的板载内存,该内存很快就会被填满,并将连续测量限制在仅几秒内。内存的读出成为数据采集速率的瓶颈。我们在此表明,由于每个离子图像中的大多数像素不包含数据,使用基于事件/神经形态相机可显著降低数据速率。因此,数据流被减少到每个离子事件点亮的像素上的强度和位置信息,以及一个指示离子到达探测器时间的时间戳。这显著提高了该方法的占空比,并为执行其他高重复率离子成像实验提供了思路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/53466fa8853c/jp2c00806_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/a09dd0abd768/jp2c00806_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/780d7f33ea8d/jp2c00806_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/514b46af8431/jp2c00806_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/2bff87881117/jp2c00806_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/53466fa8853c/jp2c00806_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/a09dd0abd768/jp2c00806_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/780d7f33ea8d/jp2c00806_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/514b46af8431/jp2c00806_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/2bff87881117/jp2c00806_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ff96/8996233/53466fa8853c/jp2c00806_0005.jpg

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本文引用的文献

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Measuring Transient Reaction Rates from Nonstationary Catalysts.测量非稳态催化剂的瞬态反应速率。
ACS Catal. 2020 Dec 4;10(23):14056-14066. doi: 10.1021/acscatal.0c03773. Epub 2020 Nov 17.
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Nature. 2018 Jun;558(7709):280-283. doi: 10.1038/s41586-018-0188-x. Epub 2018 Jun 13.
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Coincidence velocity map imaging using Tpx3Cam, a time stamping optical camera with 1.5 ns timing resolution.使用Tpx3Cam的重合速度映射成像,Tpx3Cam是一种具有1.5纳秒定时分辨率的时间标记光学相机。
Rev Sci Instrum. 2017 Nov;88(11):113104. doi: 10.1063/1.4996888.
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