Silica Meets Tannic Acid: Designing Green Nanoplatforms for Environment Preservation.

Hybrid tannic acid-silica-based porous nanoparticles, TA-SiO NPs, have been synthesized under mild conditions in the presence of green and renewable tannic acid biopolymer, a glycoside polymer of gallic acid present in a large part of plants. Tannic acid (TA) was exploited as both a structuring directing agent and green chelating site for heavy metal ions recovery from aqueous solutions. Particles morphologies and porosity were easily tuned by varying the TA initial amount. The sample produced with the largest TA amount showed a specific surface area an order of magnitude larger than silica nanoparticles. The adsorption performance was investigated by using TA-SiO NPs as adsorbents for copper (II) ions from an aqueous solution. The effects of the initial Cu ions concentration and the pH values on the adsorption capability were also investigated. The resulting TA-SiO NPs exhibited a different adsorption behaviour towards Cu, which was demonstrated through different tests. The largest adsorption (i.e., ~50 wt% of the initial Cu amount) was obtained with the more porous nanoplatforms bearing a higher final TA content. The TA-nanoplatforms, stable in pH value around neutral conditions, can be easily produced and their use would well comply with a green strategy to reduce wastewater pollution.