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用于燃料电池应用的阴离子交换膜:综述

Anion Exchange Membranes for Fuel Cell Application: A Review.

作者信息

Das Gautam, Choi Ji-Hyeok, Nguyen Phan Khanh Thinh, Kim Dong-Joo, Yoon Young Soo

机构信息

Department of Polymer Science and Engineering, School of Applied Chemical Engineering, Kyungpook National University, Daegu 41566, Korea.

Department of Materials Science and Engineering, Gachon University, Seongnam 13120, Gyeonggi-do, Korea.

出版信息

Polymers (Basel). 2022 Mar 16;14(6):1197. doi: 10.3390/polym14061197.

Abstract

The fuel cell industry is the most promising industry in terms of the advancement of clean and safe technologies for sustainable energy generation. The polymer electrolyte membrane fuel cell is divided into two parts: anion exchange membrane fuel cells (AEMFCs) and proton exchange membrane fuel cells (PEMFCs). In the case of PEMFCs, high-power density was secured and research and development for commercialization have made significant progress. However, there are technical limitations and high-cost issues for the use of precious metal catalysts including Pt, the durability of catalysts, bipolar plates, and membranes, and the use of hydrogen to ensure system stability. On the contrary, AEMFCs have been used as low-platinum or non-platinum catalysts and have a low activation energy of oxygen reduction reaction, so many studies have been conducted to find alternatives to overcome the problems of PEMFCs in the last decade. At the core of ensuring the power density of AEMFCs is the anion exchange membrane (AEM) which is less durable and less conductive than the cation exchange membrane. AEMFCs are a promising technology that can solve the high-cost problem of PEMFCs that have reached technological saturation and overcome technical limitations. This review focuses on the various aspects of AEMs for AEMFCs application.

摘要

就推进用于可持续能源生产的清洁安全技术而言,燃料电池行业是最具前景的行业。聚合物电解质膜燃料电池分为两部分:阴离子交换膜燃料电池(AEMFC)和质子交换膜燃料电池(PEMFC)。在PEMFC方面,已确保了高功率密度,并且商业化研发取得了重大进展。然而,使用包括铂在内的贵金属催化剂存在技术限制和高成本问题,催化剂、双极板和膜的耐久性,以及使用氢气以确保系统稳定性。相反,AEMFC已被用作低铂或非铂催化剂,并且氧还原反应的活化能较低,因此在过去十年中进行了许多研究以寻找替代方案来克服PEMFC的问题。确保AEMFC功率密度的核心是阴离子交换膜(AEM),它比阳离子交换膜的耐久性和导电性更低。AEMFC是一种有前景的技术,可以解决已达到技术饱和的PEMFC的高成本问题并克服技术限制。本综述聚焦于用于AEMFC应用的AEM的各个方面。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a60f/8955432/677d11426286/polymers-14-01197-g003.jpg

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