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用于防污应用的3D打印金属氧化物-聚合物复合材料

3D Printed Metal Oxide-Polymer Composite Materials for Antifouling Applications.

作者信息

Bouranta Andrianna, Tudose Ioan Valentin, Georgescu Luciana, Karaiskou Anna, Vrithias Nikolaos Rafail, Viskadourakis Zacharias, Kenanakis George, Sfakaki Efsevia, Mitrizakis Nikolaos, Strakantounas George, Papandroulakis Nikolaos, Romanitan Cosmin, Pachiu Cristina, Tutunaru Oana, Barbu-Tudoran Lucian, Suchea Mirela Petruta, Koudoumas Emmanouel

机构信息

Center of Materials Technology and Photonics, Hellenic Mediterranean University, 71410 Heraklion, Greece.

Institute of Electronic Structure and Laser, Foundation for Research & Technology-Hellas, 70013 Heraklion, Greece.

出版信息

Nanomaterials (Basel). 2022 Mar 10;12(6):917. doi: 10.3390/nano12060917.

Abstract

Current technology to prevent biofouling usually relies on the use of toxic, biocide-containing materials, which can become a serious threat to marine ecosystems, affecting both targeted and nontargeted organisms. Therefore, the development of broad-spectrum, less toxic antifouling materials is a challenge for researchers; such materials would be quite important in applications like aquaculture. In this respect, surface chemistry, physical properties, durability and attachment scheme can play a vital role in the performance of the materials. In this work, acrylonitrile butadiene styrene (ABS)/micro ZnO or nano ZnO composite lattices with different metal oxide contents were developed using 3D printing. Their antifouling behavior was examined with respect to aquaculture applications by monitoring growth on them of the diatoms sp. and the monocellular algae sp. with image analysis techniques. As shown, the presence of metal oxides in the composite materials can bring about antifouling ability at particular concentrations. The present study showed promising results, but further improvements are needed.

摘要

当前防止生物污损的技术通常依赖于使用含毒的杀生剂材料,这可能对海洋生态系统构成严重威胁,影响目标生物和非目标生物。因此,开发广谱、低毒的防污材料对研究人员来说是一项挑战;这类材料在水产养殖等应用中非常重要。在这方面,表面化学、物理性质、耐久性和附着方案对材料的性能起着至关重要的作用。在这项工作中,使用3D打印技术制备了具有不同金属氧化物含量的丙烯腈-丁二烯-苯乙烯(ABS)/微米级ZnO或纳米级ZnO复合晶格。通过图像分析技术监测硅藻属和单细胞藻类在其表面的生长情况,考察了它们在水产养殖应用方面的防污性能。结果表明,复合材料中金属氧化物的存在在特定浓度下可带来防污能力。本研究显示出了有前景的结果,但仍需进一步改进。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a4e/8949573/b523954a3b96/nanomaterials-12-00917-g001.jpg

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