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规模化多阳极共享阴极微生物燃料电池同步处理多种实际废水并发电。

Scaled-up multi-anode shared cathode microbial fuel cell for simultaneous treatment of multiple real wastewaters and power generation.

机构信息

Hohai University, College of Environment, No. 1 Xikang Road, 210098, Nanjing, PR China.

Hohai University, College of Environment, No. 1 Xikang Road, 210098, Nanjing, PR China.

出版信息

Chemosphere. 2022 Jul;299:134401. doi: 10.1016/j.chemosphere.2022.134401. Epub 2022 Mar 23.

Abstract

Microbial fuel cell (MFC) is lauded for its capacity to valorize organic substrates in wastes, providing a solution to environmental pollution and energy crisis. While different types of organic substrates affect removal efficiency and current output, most MFCs are designed to only be able to utilize one type of wastewater. However, many real wastewater treatment sites generate more than one type of wastewater which hinders the installation of most MFCs. This study aimed to investigate the performance of the novel-designed multi-anode shared cathode MFC (MASC-MFC) compared with a standard single anode/cathode MFC (SAC-MFC) and the simultaneous treatment of different types of real wastewaters (sewage, slaughterhouse, and hospital) in one MFC unit. The MASC-MFC (9025 mW/m at 23.332 mA/m) produced 1.7 times and 1.6 times higher in power density and current density and 2.2 times lower in internal resistance than the standard single anode/cathode MFC (SAC-MFC). A maximum COD removal efficiency of 62.7% was achieved with synthetic wastewater. Feeding the MASC-MFC with multiple real wastewaters decreased maximum power density 3.5 (2599 mW/m) times and increased internal resistance 2.7 times. Stable current generation 1.575 mA was achieved over 300 h despite the different and complex wastewater physio-chemical compositions. The MASC-MFC achieved over 40% and approximately 30% coulombic efficiency independently in all the anode chambers irrespective of the type of real wastewater used, demonstrating the MASC-MFC's capacity to treat different real wastewaters with the added benefit of electricity production.

摘要

微生物燃料电池(MFC)因其能够将有机废物转化为有价值的物质而受到赞誉,为解决环境污染和能源危机提供了一种解决方案。不同类型的有机废物会影响去除效率和电流输出,但大多数 MFC 只能利用一种类型的废水。然而,许多实际的废水处理场所会产生多种类型的废水,这阻碍了大多数 MFC 的安装。本研究旨在研究新型多阳极共享阴极 MFC(MASC-MFC)与标准单阳极/阴极 MFC(SAC-MFC)的性能,并在一个 MFC 单元中同时处理不同类型的实际废水(污水、屠宰场和医院)。与标准单阳极/阴极 MFC(SAC-MFC)相比,MASC-MFC(23.332 mA/m 时为 9025 mW/m)的功率密度和电流密度分别提高了 1.7 倍和 1.6 倍,内阻降低了 2.2 倍。在处理合成废水时,最大 COD 去除效率达到 62.7%。用多种实际废水喂养 MASC-MFC 会使最大功率密度降低 3.5 倍(2599 mW/m),内阻增加 2.7 倍。尽管废水的理化性质复杂多样,但 MASC-MFC 仍能在 300 小时内稳定产生 1.575 mA 的电流。无论使用哪种实际废水,MASC-MFC 都能在所有阳极室中实现 40%以上和近 30%的库仑效率,证明了 MASC-MFC 有能力处理不同的实际废水,并具有发电的额外好处。

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