Department of Fine Arts, National Taiwan University, No.1, Shida Rd., Da'an Dist., Taipei, 10645, Taiwan.
Department of Chemistry, National Taiwan University, Tingchow Rd., Taipei, 10617, Taiwan.
Anal Sci. 2022 Mar;38(3):483-495. doi: 10.2116/analsci.21SAR03. Epub 2022 Apr 1.
This review provides a general understanding of Raman spectroscopy for use in the identification of pigments and dyes. The methodologies associated with a number of different related applications are also summarized. The first part of this review clarifies our basic knowledge regarding natural minerals and pigments. The second part discusses the fundamentals of currently used Raman spectroscopy, including surface-enhanced Raman scattering, μ-Raman spectroscopy, Raman imaging and spatially offset Raman spectroscopy. The third part focuses on recent applications, including the identification and analysis of various pigments and dyes that are used in paintings and related artworks. These studies show that Raman spectroscopy has great potential for use as a method for the rapid, non-destructive identification of such substances.
这篇综述提供了对拉曼光谱在颜料和染料鉴定中应用的总体理解。还总结了与许多不同相关应用相关的方法。本综述的第一部分阐明了我们关于天然矿物和颜料的基本知识。第二部分讨论了当前使用的拉曼光谱学的基础原理，包括表面增强拉曼散射、微拉曼光谱学、拉曼成像和空间偏移拉曼光谱学。第三部分侧重于最近的应用，包括鉴定和分析用于绘画和相关艺术品中的各种颜料和染料。这些研究表明，拉曼光谱法具有作为一种快速、非破坏性鉴定这些物质的方法的巨大潜力。
