Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
Org Lett. 2022 Apr 15;24(14):2660-2664. doi: 10.1021/acs.orglett.2c00704. Epub 2022 Apr 4.
A copper-catalyzed borylation of propargyl dichlorides was developed under mild reaction conditions. The corresponding chloro-substituted allenyl-Bdan products were obtained in good yields. The utilities of allenyl-Bdan products were examined by their diverse derivatizations.
发展了一种温和反应条件下的炔丙基二氯代物的铜催化硼化反应。以良好的收率得到相应的氯取代烯丙基-Bdan 产物。通过其多样的衍生化反应考察了烯丙基-Bdan 产物的实用性。
