Geochemical characteristics of strontium isotopes in a coastal watershed: implications for anthropogenic influenced chemical weathering and export flux.

Coastal watershed are essential in transporting dissolved loads from terrestrial biogeochemical process of surface environment to the adjacent oceans. The solute chemistry of coastal river water contains significant information about environmental processes under the impact of both natural lithology and anthropogenic pressure. In this study, strontium (Sr) isotopes and water chemistry data of the Jiulongjiang (JLJ) river water were analyzed in detail to trace the contribution of bedrock weathering, and quantify Sr flux to the East China Sea (ECS). The dissolved Sr contents ranged 0.07-0.90 μmol L and greatly fluctuated where tributaries encountered, and Sr/Sr values relatively fluctuated between 0.7140 and 0.7514. Silicate weathering was identified to be the predominant contribution of riverine dissolved loads. Strontium flux to the ocean in dry season was estimated to be 689.2 tons per year, implying an essential influence on oceanic strontium evolution. In accordance with forward model, the silicate weathering rate and CO consumption rate were 55.7 tons km per year and 16.9 × 10 mol km per year, respectively, slightly higher than world average. Considering anthropogenic impacts alongside the river, the integrated effect of lower runoff and longer retention time of river water in dry season may aggravate weathering processes. Although CO sink by silicate weathering in JLJ seems less than the sink in world's central reservoirs, it should still be taken into consideration for coastal carbon budget. These findings highlight the use of geochemical characteristics of strontium and its isotopes in identifying weathering process and output flux to the ocean, which provides basic data for sustainable coastal water resource management.