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简便合成锚定在还原氧化石墨烯上的CoFeO@SiO纳米颗粒用于高效电磁波吸收

Facile synthesis of CoFeO@SiO nanoparticles anchored on reduced graphene oxide for highly efficient electromagnetic wave absorption.

作者信息

Lu Hechao, Li Chenyu, Chen Kaiwen, He Qinting, Ren Fang, Wu Juan, Dai Renxing

机构信息

Jiangsu Key Laboratory of E-waste Recycling, School of Resources and Environmental Engineering, Jiangsu University of Technology Changzhou 213001 China

National Special Superfine Powder Engineering Research Center, Nanjing University of Science and Technology Nanjing 210094 China.

出版信息

RSC Adv. 2025 Jul 21;15(32):25872-25884. doi: 10.1039/d5ra03579a.

Abstract

In this study, a ternary composite material composed of CoFeO@SiO nanospheres and reduced graphene oxide (RGO) was successfully synthesized through a facile route. The composites exhibited a layered "sandwich" structure, where CoFeO@SiO nanospheres were anchored onto the surface of RGO nanosheets. The microstructure and electromagnetic wave absorption properties of the synthesized CoFeO@SiO/RGO were systematically investigated. Results revealed that the composites possessed excellent electromagnetic wave absorption performance, with a minimum reflection loss (RL) of -27.7 dB at 13.02 GHz for a thickness of 1.8 mm. Furthermore, the composites exhibited a broad absorption bandwidth of up to 14.52 GHz (3.48-18 GHz) with reflection losses less than -10 dB over a thickness range of 1.5 to 5.0 mm, covering the S-Ku band. The enhanced absorption performance could be attributed to the optimized impedance matching and synergistic electromagnetic loss mechanisms. The CoFeO@SiO/RGO composites demonstrated balanced dielectric and magnetic loss, enabled by the effective interaction of electromagnetic parameters. These results indicate that the developed composites provide a promising candidate for high-performance microwave absorbing materials with lightweight, strong absorption, and broad bandwidth characteristics, potentially applicable in military stealth technology, electromagnetic compatibility enhancement, and ecological protection.

摘要

在本研究中,通过一种简便的方法成功合成了由CoFeO@SiO纳米球和还原氧化石墨烯(RGO)组成的三元复合材料。该复合材料呈现出层状“三明治”结构,其中CoFeO@SiO纳米球锚定在RGO纳米片的表面。对合成的CoFeO@SiO/RGO的微观结构和电磁波吸收性能进行了系统研究。结果表明,该复合材料具有优异的电磁波吸收性能,在厚度为1.8 mm时,13.02 GHz处的最小反射损耗(RL)为-27.7 dB。此外,该复合材料在1.5至5.0 mm的厚度范围内表现出高达14.52 GHz(3.48 - 18 GHz)的宽吸收带宽,反射损耗小于-10 dB,覆盖了S - Ku波段。吸收性能的增强可归因于优化的阻抗匹配和协同电磁损耗机制。CoFeO@SiO/RGO复合材料通过电磁参数的有效相互作用表现出平衡的介电和磁损耗。这些结果表明,所开发的复合材料为具有轻质、强吸收和宽带宽特性的高性能微波吸收材料提供了一个有前景的候选材料,可能适用于军事隐身技术、电磁兼容性增强和生态保护。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/41f6/12278383/08194c9a9c6d/d5ra03579a-f1.jpg

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