• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

含钯金属聚合物对水中一氧化碳的电催化还原

Electrocatalytic Reduction of CO in Water by a Palladium-Containing Metallopolymer.

作者信息

Teixeira Marcos F S, Olean-Oliveira André, Anastácio Fernanda C, David-Parra Diego N, Cardoso Celso X

机构信息

Department of Chemistry and Biochemistry, School of Science and Technology, Sao Paulo State University (UNESP), Presidente Prudente CEP 19060-900, SP, Brazil.

Department of Physics, School of Science and Technology, Sao Paulo State University (UNESP), Presidente Prudente CEP 19060-900, SP, Brazil.

出版信息

Nanomaterials (Basel). 2022 Apr 2;12(7):1193. doi: 10.3390/nano12071193.

DOI:10.3390/nano12071193
PMID:35407311
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9000595/
Abstract

The palladium-salen complex was immobilized by electropolymerization onto a Pt disc electrode and applied as an electrocatalyst for the reduction of CO in an aqueous solution. Linear sweep voltammetry measurements and rotating disk experiments were carried out to study the electrochemical reduction of carbon dioxide. The onset overpotential for carbon dioxide reduction was approximately -0.22 V vs. NHE on the poly-Pd(salen) modified electrode. In addition, by combining the electrochemical study with a kinetic study, the rate-determining step of the electrochemical CO reduction reaction (CORR) was found to be the radial reduction of carbon dioxide to the CO adsorbed on the metal.

摘要

通过电聚合将钯-席夫碱配合物固定在铂盘电极上，并用作水溶液中一氧化碳还原的电催化剂。进行线性扫描伏安法测量和旋转圆盘实验以研究二氧化碳的电化学还原。在聚钯（席夫碱）修饰电极上，二氧化碳还原的起始过电位相对于标准氢电极约为-0.22V。此外，通过将电化学研究与动力学研究相结合，发现电化学一氧化碳还原反应（CORR）的速率决定步骤是二氧化碳向吸附在金属上的一氧化碳的径向还原。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/a786945fbc83/nanomaterials-12-01193-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/d07693d58cd9/nanomaterials-12-01193-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/bda6ad5fdf55/nanomaterials-12-01193-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/74e72b0d0522/nanomaterials-12-01193-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/f570edfd2e66/nanomaterials-12-01193-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/6817166df546/nanomaterials-12-01193-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/7f098741c71c/nanomaterials-12-01193-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/a786945fbc83/nanomaterials-12-01193-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/d07693d58cd9/nanomaterials-12-01193-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/bda6ad5fdf55/nanomaterials-12-01193-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/74e72b0d0522/nanomaterials-12-01193-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/f570edfd2e66/nanomaterials-12-01193-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/6817166df546/nanomaterials-12-01193-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/7f098741c71c/nanomaterials-12-01193-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6fc3/9000595/a786945fbc83/nanomaterials-12-01193-g006.jpg

相似文献

1
Electrocatalytic Reduction of CO in Water by a Palladium-Containing Metallopolymer.含钯金属聚合物对水中一氧化碳的电催化还原
Nanomaterials (Basel). 2022 Apr 2;12(7):1193. doi: 10.3390/nano12071193.
2
Partially Oxidized Palladium Nanodots for Enhanced Electrocatalytic Carbon Dioxide Reduction.部分氧化钯纳米点用于增强电催化二氧化碳还原。
Chem Asian J. 2018 Oct 4;13(19):2800-2804. doi: 10.1002/asia.201800946. Epub 2018 Aug 19.
3
How palladium inhibits CO poisoning during electrocatalytic formic acid oxidation and carbon dioxide reduction.钯在电催化甲酸氧化和二氧化碳还原过程中如何抑制一氧化碳中毒。
Nat Commun. 2022 Jan 10;13(1):38. doi: 10.1038/s41467-021-27793-5.
4
Electrocatalytic Reduction of Carbon Dioxide to Carbon Monoxide by a Polymerized Film of an Alkynyl-Substituted Rhenium(I) Complex.炔基取代铼（I）配合物聚合膜对二氧化碳的电催化还原为一氧化碳
ChemCatChem. 2013 Jul;5(7):1790-1796. doi: 10.1002/cctc.201200904. Epub 2013 Apr 12.
5
Transient Effects Caused by Gas Depletion during Carbon Dioxide Electroreduction.二氧化碳电还原过程中气体消耗引起的瞬态效应。
Langmuir. 2022 Jan 25;38(3):1020-1033. doi: 10.1021/acs.langmuir.1c02540. Epub 2022 Jan 11.
6
Influence of Water Molecules on CO Reduction at the Pt Electrocatalyst in the Membrane Electrode Assembly System.水分子对膜电极组件系统中铂电催化剂上一氧化碳还原的影响。
ACS Appl Mater Interfaces. 2023 Sep 13;15(36):42676-42684. doi: 10.1021/acsami.3c09131. Epub 2023 Aug 29.
7
Unraveling the Interfacial Polarization Effect between Pd and Polymeric Carbon Nitride toward Efficient CO Electroreduction to CO.揭示钯与聚合氮化碳之间的界面极化效应以实现高效的一氧化碳电还原为一氧化碳
ACS Appl Mater Interfaces. 2022 Mar 16;14(10):12314-12322. doi: 10.1021/acsami.2c00133. Epub 2022 Mar 3.
8
Electrocatalytic CO Reduction with a Binuclear Bis-Terpyridine Pyrazole-Bridged Cobalt Complex.双核双三联吡啶吡唑桥联钴配合物电催化 CO 还原。
Chemistry. 2023 Feb 10;29(9):e202202361. doi: 10.1002/chem.202202361. Epub 2023 Jan 11.
9
Electrochemical Reduction of CO at Coinage Metal Nanodendrites in Aqueous Ethanolamine.乙醇胺水溶液中硬币金属纳米枝晶上CO的电化学还原
Chemistry. 2021 Jan 18;27(4):1346-1355. doi: 10.1002/chem.202003039. Epub 2020 Dec 15.
10
ZIF/Co-CN with enhanced electrocatalytic reduction of carbon dioxide activity by the photoactivation process.通过光活化过程增强电催化还原二氧化碳活性的沸石咪唑酯骨架结构材料/共价有机网络
Nanoscale. 2021 Sep 7;13(33):14089-14095. doi: 10.1039/d1nr03119h. Epub 2021 Aug 9.

引用本文的文献

1
Advanced Nanostructured Materials for Electrocatalysis in Lithium-Sulfur Batteries.用于锂硫电池电催化的先进纳米结构材料
Nanomaterials (Basel). 2022 Dec 6;12(23):4341. doi: 10.3390/nano12234341.

本文引用的文献

1
Solvents and Supporting Electrolytes in the Electrocatalytic Reduction of CO.一氧化碳电催化还原中的溶剂与支持电解质
iScience. 2019 Sep 27;19:135-160. doi: 10.1016/j.isci.2019.07.014. Epub 2019 Jul 16.
2
Progress and Perspectives of Electrochemical CO Reduction on Copper in Aqueous Electrolyte.电化学 CO 还原在水溶液电解质中铜上的进展与展望。
Chem Rev. 2019 Jun 26;119(12):7610-7672. doi: 10.1021/acs.chemrev.8b00705. Epub 2019 May 22.
3
Copper Metallopolymer Catalyst for the Electrocatalytic Hydrogen Evolution Reaction (HER).
用于电催化析氢反应（HER）的铜金属聚合物催化剂。
Polymers (Basel). 2019 Jan 10;11(1):110. doi: 10.3390/polym11010110.
4
A chemiresistor sensor based on a cobalt(salen) metallopolymer for dissolved molecular oxygen.基于钴（席夫碱）金属聚合物的化学电阻传感器用于溶解分子氧。
Talanta. 2018 Dec 1;190:119-125. doi: 10.1016/j.talanta.2018.07.080. Epub 2018 Jul 25.
5
Boosting Formate Production in Electrocatalytic CO Reduction over Wide Potential Window on Pd Surfaces.在 Pd 表面上的宽电位窗口中电催化 CO 还原中促进甲酸盐生成。
J Am Chem Soc. 2018 Feb 28;140(8):2880-2889. doi: 10.1021/jacs.7b12506. Epub 2018 Feb 20.
6
Understanding of Strain Effects in the Electrochemical Reduction of CO : Using Pd Nanostructures as an Ideal Platform.理解 CO 的电化学还原中的应变效应：以 Pd 纳米结构为理想平台。
Angew Chem Int Ed Engl. 2017 Mar 20;56(13):3594-3598. doi: 10.1002/anie.201612617. Epub 2017 Feb 20.
7
Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center.利用地球丰富金属配合物的电化学和光化学还原 CO2 的分子催化。通过改变金属中心选择性地生成 CO 与 HCOOH。
J Am Chem Soc. 2015 Sep 2;137(34):10918-21. doi: 10.1021/jacs.5b06535. Epub 2015 Aug 19.
8
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels.二氧化碳电还原生产低碳燃料用催化剂研究进展。
Chem Soc Rev. 2014 Jan 21;43(2):631-75. doi: 10.1039/c3cs60323g.
9
Opportunities and challenges for a sustainable energy future.可持续能源未来的机遇与挑战。
Nature. 2012 Aug 16;488(7411):294-303. doi: 10.1038/nature11475.
10
Turnover numbers, turnover frequencies, and overpotential in molecular catalysis of electrochemical reactions. Cyclic voltammetry and preparative-scale electrolysis.电化学反应中分子催化的转换数、转换频率和超电势。循环伏安法和制备规模电解。
J Am Chem Soc. 2012 Jul 11;134(27):11235-42. doi: 10.1021/ja303560c. Epub 2012 Jun 27.