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用于分析固体氧化物燃料电池阴极材料稳定性和降解机理的X射线光电子能谱技术综述

A Review of X-ray Photoelectron Spectroscopy Technique to Analyze the Stability and Degradation Mechanism of Solid Oxide Fuel Cell Cathode Materials.

作者信息

Anwar Mustafa, Shaikh Abdul Muhammed Ali, Khan Uneeb Masood, Hassan Muhammad, Khoja Asif Hussain, Muchtar Andanastuti

机构信息

U.S.-Pakistan Center for Advanced Studies in Energy, National University of Sciences and Technology, H-12, Islamabad 44000, Pakistan.

Fuel Cell Institute, Universiti Kebangsaan Malaysia, Bangi 43600, Malaysia.

出版信息

Materials (Basel). 2022 Mar 30;15(7):2540. doi: 10.3390/ma15072540.

DOI:10.3390/ma15072540
PMID:35407872
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9000260/
Abstract

Nondestructive characterization of solid oxide fuel cell (SOFC) materials has drawn attention owing to the advances in instrumentation that enable in situ characterization during high-temperature cell operation. X-ray photoelectron spectroscopy (XPS) is widely used to investigate the surface of SOFC cathode materials because of its excellent chemical specificity and surface sensitivity. The XPS can be used to analyze the elemental composition and oxidation state of cathode layers from the surface to a depth of approximately 5-10 nm. Any change in the chemical state of the SOFC cathode at the surface affects the migration of oxygen ions to the cathode/electrolyte interface via the cathode layer and causes performance degradation. The objective of this article is to provide a comprehensive review of the adoption of XPS for the characterization of SOFC cathode materials to understand its degradation mechanism in absolute terms. The use of XPS to confirm the chemical stability at the interface and the enrichment of cations on the surface is reviewed. Finally, the strategies adopted to improve the structural stability and electrochemical performance of the LSCF cathode are also discussed.

摘要

由于仪器技术的进步使得在高温电池运行过程中能够进行原位表征，固体氧化物燃料电池（SOFC）材料的无损表征受到了关注。X射线光电子能谱（XPS）因其出色的化学特异性和表面灵敏度而被广泛用于研究SOFC阴极材料的表面。XPS可用于分析阴极层从表面到约5-10nm深度的元素组成和氧化态。SOFC阴极表面化学状态的任何变化都会影响氧离子通过阴极层向阴极/电解质界面的迁移，并导致性能下降。本文的目的是全面综述XPS在SOFC阴极材料表征中的应用，以便从绝对意义上理解其降解机制。综述了使用XPS确认界面处的化学稳定性和表面阳离子富集的情况。最后，还讨论了为提高LSCF阴极的结构稳定性和电化学性能而采取的策略。

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