• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

钆替代的镍锌钴铁氧体的结构、热力学及多功能特性研究

Investigation on structure, thermodynamic and multifunctional properties of Ni-Zn-Co ferrite for Gd substitution.

作者信息

Hossain M D, Jamil A T M K, Hossain Md Sarowar, Ahmed S J, Das H N, Rashid R, Hakim M A, Khan M N I

机构信息

Department of Physics, Dhaka University of Engineering and Technology (DUET) Gazipur Bangladesh.

S N Bose National Centre for Basic Sciences Kolkata 700106 West Bengal India.

出版信息

RSC Adv. 2022 Feb 7;12(8):4656-4671. doi: 10.1039/d1ra04762k. eCollection 2022 Feb 3.

DOI:10.1039/d1ra04762k
PMID:35425488
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8981410/
Abstract

This study presents a modification of structure-dependent elastic, thermodynamic, magnetic, transport and magneto-dielectric properties of a Ni-Zn-Co ferrite tailored by Gd substitution at the B-site replacing Fe ions. The synthesized composition of NiZnCoFe Gd O (0 ≤ ≤ 0.12) crystallized with a single-phase cubic spinel structure that belongs to the 3̄ space group. The average particle size decreases due to Gd substitution at Fe. Raman and IR spectroscopy studies illustrate phase purity, lattice dynamics with cation disorders and thermodynamic conditions inside the studied samples at room temperature (RT = 300 K). Ferromagnetic to paramagnetic phase transition was observed in all samples where Curie temperature ( ) decreases from 731 to 711 K for Gd substitution in Ni-Zn-Co ferrite. In addition, Gd substitution reinforces to decrease the A-B exchange interaction. Temperature-dependent DC electrical resistivity ( ) and temperature coefficient of resistance (TCR) have been surveyed with the variation of the grain size. The frequency-dependent dielectric properties and electric modulus at RT for all samples were observed from 20 Hz to 100 MHz and the conduction relaxation processes were found to spread over an extensive range of frequencies with the increase in the amount of Gd in the Ni-Zn-Co ferrite. The RLC behavior separates the zone of frequencies ranging from resistive to capacitive regions in all the studied samples. Finally, the matching impedance (/ ) for all samples was evaluated over an extensive range of frequencies for the possible miniaturizing application.

摘要

本研究提出了一种通过在B位用Gd替代Fe离子来定制Ni-Zn-Co铁氧体的结构相关弹性、热力学、磁性、输运和磁电介质特性的方法。合成的NiZnCoFeGdO（0≤≤0.12）成分结晶为单相立方尖晶石结构，属于3̄空间群。由于Gd替代Fe，平均粒径减小。拉曼光谱和红外光谱研究表明了所研究样品在室温（RT = 300 K）下的相纯度、阳离子无序的晶格动力学和热力学条件。在所有样品中都观察到了从铁磁到顺磁的相变，其中Ni-Zn-Co铁氧体中Gd替代导致居里温度（）从731 K降至711 K。此外，Gd替代增强了A-B交换相互作用的减弱。随着晶粒尺寸的变化，测量了温度依赖的直流电阻率（）和电阻温度系数（TCR）。在室温下，观察了所有样品从20 Hz到100 MHz的频率依赖介电特性和电模量，并且发现随着Ni-Zn-Co铁氧体中Gd含量的增加，传导弛豫过程在很宽的频率范围内扩展。RLC行为在所有研究样品中分离了从电阻区到电容区的频率范围。最后，在很宽的频率范围内评估了所有样品的匹配阻抗（/），以用于可能的小型化应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/533c25e050d8/d1ra04762k-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/43a478365ec7/d1ra04762k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/4c05d73eb5d5/d1ra04762k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/c634222febbd/d1ra04762k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/f61461fd5e09/d1ra04762k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/f7001ebb4424/d1ra04762k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/40084dac13b4/d1ra04762k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/f230d2526433/d1ra04762k-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/ae964460b606/d1ra04762k-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/e867ebc07be2/d1ra04762k-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/5c6d956a3c60/d1ra04762k-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/0c7ab3ff0498/d1ra04762k-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/652d6d93efd5/d1ra04762k-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/533c25e050d8/d1ra04762k-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/43a478365ec7/d1ra04762k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/4c05d73eb5d5/d1ra04762k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/c634222febbd/d1ra04762k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/f61461fd5e09/d1ra04762k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/f7001ebb4424/d1ra04762k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/40084dac13b4/d1ra04762k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/f230d2526433/d1ra04762k-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/ae964460b606/d1ra04762k-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/e867ebc07be2/d1ra04762k-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/5c6d956a3c60/d1ra04762k-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/0c7ab3ff0498/d1ra04762k-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/652d6d93efd5/d1ra04762k-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bd74/8981410/533c25e050d8/d1ra04762k-f13.jpg

相似文献

1
Investigation on structure, thermodynamic and multifunctional properties of Ni-Zn-Co ferrite for Gd substitution.钆替代的镍锌钴铁氧体的结构、热力学及多功能特性研究
RSC Adv. 2022 Feb 7;12(8):4656-4671. doi: 10.1039/d1ra04762k. eCollection 2022 Feb 3.
2
Synthesis and investigation of structural, elastic, and electrical properties of cobalt and magnesium substituted Ni-Zn spinel ferrite nanoparticles.钴和镁取代的镍锌尖晶石铁氧体纳米颗粒的结构、弹性和电学性质的合成与研究
J Phys Condens Matter. 2023 Jul 21;35(42). doi: 10.1088/1361-648X/ace6ed.
3
Magnetic and spectroscopic properties of Ni-Zn-Al ferrite spinel: from the nanoscale to microscale.镍锌铝铁氧体尖晶石的磁性和光谱性质：从纳米尺度到微米尺度
RSC Adv. 2020 Sep 18;10(57):34556-34580. doi: 10.1039/d0ra05522k. eCollection 2020 Sep 16.
4
Sonochemical synthesis of Gd doped CoFeO spinel ferrite nanoparticles and its physical properties.钆掺杂钴铁氧体尖晶石纳米颗粒的声化学合成及其物理性质。
Ultrason Sonochem. 2018 Jan;40(Pt A):773-783. doi: 10.1016/j.ultsonch.2017.08.024. Epub 2017 Aug 24.
5
Correlation among the structural, electric and magnetic properties of Al substituted Ni-Zn-Co ferrites.铝取代镍锌钴铁氧体的结构、电学和磁学性能之间的相关性。
RSC Adv. 2022 May 18;12(24):15167-15179. doi: 10.1039/d1ra09354a. eCollection 2022 May 17.
6
Unveiling the impact of Ni/Y co-substitution on the structural, dielectric, and impedance properties of multiferroic spinel ferrite for hydroelectric cell application.揭示镍/钇共取代对用于水电电池的多铁性尖晶石铁氧体的结构、介电和阻抗特性的影响。
Phys Chem Chem Phys. 2023 Aug 16;25(32):21280-21296. doi: 10.1039/d3cp02339g.
7
Influence of neodymium substitution on structural, magnetic and spectroscopic properties of Ni-Zn-Al nano-ferrites.钕取代对镍锌铝纳米铁氧体结构、磁性和光谱性质的影响。
RSC Adv. 2021 Apr 8;11(22):13256-13268. doi: 10.1039/d0ra10140k. eCollection 2021 Apr 7.
8
Crystal chemistry and single-phase synthesis of Gd substituted Co-Zn ferrite nanoparticles for enhanced magnetic properties.用于增强磁性的钆取代钴锌铁氧体纳米颗粒的晶体化学与单相合成
RSC Adv. 2018 Jul 16;8(44):25258-25267. doi: 10.1039/c8ra04282a. eCollection 2018 Jul 9.
9
Evaluation of Structural, Magnetic, and Electromagnetic Properties of Co-Substituted NiCuZn Ferrites.钴取代镍铜锌铁氧体的结构、磁性和电磁性能评估。
ACS Omega. 2023 Aug 8;8(33):30508-30518. doi: 10.1021/acsomega.3c03757. eCollection 2023 Aug 22.
10
Effect of Cd Substitution on Structural-Magnetic and Dielectric Properties of Ni-Cu-Zn Spinel Ferrite Nanomaterials by Sol-Gel.镉取代对溶胶-凝胶法制备的镍-铜-锌尖晶石铁氧体纳米材料结构磁性和介电性能的影响
Molecules. 2023 Aug 17;28(16):6110. doi: 10.3390/molecules28166110.

引用本文的文献

1
An experimental investigation of vibrational, optical, and dielectric properties of Li-Mg ferrite for potential high-frequency and optoelectronic applications.用于潜在高频和光电子应用的锂镁铁氧体的振动、光学和介电性能的实验研究。
RSC Adv. 2025 Jul 29;15(33):26873-26885. doi: 10.1039/d5ra03292j. eCollection 2025 Jul 25.
2
Unveiling the role of sintering temperatures in the physical properties of Cu-Mg ferrite nanoparticles for photocatalytic application.揭示烧结温度在用于光催化应用的铜镁铁氧体纳米颗粒物理性质中的作用。
Heliyon. 2024 Dec 2;10(23):e40771. doi: 10.1016/j.heliyon.2024.e40771. eCollection 2024 Dec 15.
3

本文引用的文献

1
Investigation of the structural, optical, elastic and electrical properties of spinel LiZnFeO nanoparticles annealed at two distinct temperatures.对在两个不同温度下退火的尖晶石型LiZnFeO纳米颗粒的结构、光学、弹性和电学性质的研究。
RSC Adv. 2019 Dec 11;9(70):40940-40955. doi: 10.1039/c9ra07569k. eCollection 2019 Dec 9.
2
Magnetic and spectroscopic properties of Ni-Zn-Al ferrite spinel: from the nanoscale to microscale.镍锌铝铁氧体尖晶石的磁性和光谱性质：从纳米尺度到微米尺度
RSC Adv. 2020 Sep 18;10(57):34556-34580. doi: 10.1039/d0ra05522k. eCollection 2020 Sep 16.
3
The structural, DC resistivity and magnetic properties of Zr and Co co-substituted NiZnFeO.
Synthesis of New Complex Ferrite LiMnFeO Chemical-Physical and Electrophysical Research.
新型复合铁氧体LiMnFeO的合成——化学物理与电物理研究
Materials (Basel). 2024 Jul 30;17(15):3754. doi: 10.3390/ma17153754.
4
Graphene nanoplatelets (GNPs): a source to bring change in the properties of Co-Ni-Gd-ferrite/GNP nanocomposites.石墨烯纳米片（GNPs）：改变钴-镍-钆铁氧体/GNP纳米复合材料性能的一个来源。
RSC Adv. 2023 Nov 22;13(49):34308-34321. doi: 10.1039/d3ra02080k.
5
Research on the physical properties of LiMnFeO spinel ferrites by the combination of optical, magnetic, and dielectric behaviors.通过光学、磁性和介电行为相结合对锂锰铁氧体尖晶石的物理性质进行研究。
RSC Adv. 2023 Mar 20;13(14):9260-9272. doi: 10.1039/d3ra00985h.
6
QCM-Based MgFeO@CaAlg Nanocomposite as a Fast Response Nanosensor for Real-Time Detection of Methylene Blue Dye.基于石英晶体微天平的MgFeO@CaAlg纳米复合材料作为用于实时检测亚甲基蓝染料的快速响应纳米传感器
Nanomaterials (Basel). 2022 Dec 25;13(1):97. doi: 10.3390/nano13010097.
7
Correlation among the structural, electric and magnetic properties of Al substituted Ni-Zn-Co ferrites.铝取代镍锌钴铁氧体的结构、电学和磁学性能之间的相关性。
RSC Adv. 2022 May 18;12(24):15167-15179. doi: 10.1039/d1ra09354a. eCollection 2022 May 17.
锆和钴共取代的镍锌铁氧体的结构、直流电阻率和磁性
Heliyon. 2019 Jun 4;5(6):e01800. doi: 10.1016/j.heliyon.2019.e01800. eCollection 2019 Jun.
4
Observation of magnetic anomalies in one-step solvothermally synthesized nickel-cobalt ferrite nanoparticles.一步溶剂热法合成镍钴铁氧体纳米颗粒中的磁异常观测
Nanoscale. 2016 Mar 7;8(9):5200-13. doi: 10.1039/c5nr06791j.
5
Monolayer assembly of ferrimagnetic Co(x)Fe(3-x)O4 nanocubes for magnetic recording.Co(x)Fe(3-x)O4 纳米立方的单层组装用于磁性记录。
Nano Lett. 2014 Jun 11;14(6):3395-9. doi: 10.1021/nl500904a. Epub 2014 May 9.
6
Distribution of cations in nanosize and bulk Co-Zn ferrites.纳米和体相 Co-Zn 铁氧体中阳离子的分布。
Nanotechnology. 2011 Aug 26;22(34):345701. doi: 10.1088/0957-4484/22/34/345701. Epub 2011 Jul 28.
7
Synthesis, magnetic and optical properties of core/shell Co1-xZnxFe2O4/SiO2 nanoparticles.核壳型 Co1-xZnxFe2O4/SiO2 纳米粒子的合成、磁性和光学性质。
Nanoscale Res Lett. 2011 Jul 20;6(1):460. doi: 10.1186/1556-276X-6-460.
8
Utility of biodegradable plasmonic nanoclusters in photoacoustic imaging.生物可降解等离子体纳米团簇在光声成像中的应用。
Opt Lett. 2010 Nov 15;35(22):3751-3. doi: 10.1364/OL.35.003751.
9
Size-dependent magnetic properties of single-crystalline multiferroic BiFeO3 nanoparticles.单晶多铁性BiFeO₃纳米颗粒的尺寸依赖性磁性能
Nano Lett. 2007 Mar;7(3):766-72. doi: 10.1021/nl063039w. Epub 2007 Feb 27.
10
Size-dependent magnetic properties of MnFe2O4 fine particles synthesized by coprecipitation.共沉淀法合成的MnFe₂O₄细颗粒的尺寸依赖性磁性能
Phys Rev B Condens Matter. 1996 Oct 1;54(13):9288-9296. doi: 10.1103/physrevb.54.9288.