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基于SnSe/SnO准核壳纳米颗粒异质界面的用于糖尿病预诊的高性能丙酮传感器。

Superior acetone sensor based on hetero-interface of SnSe/SnO quasi core shell nanoparticles for previewing diabetes.

作者信息

Jin Shicheng, Wu Di, Song Weinan, Hao Hongshun, Gao Wenyuan, Yan Shuang

机构信息

School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China.

Dalian Scientific Test and Control Technology Institute, Dalian 116001, China.

出版信息

J Colloid Interface Sci. 2022 Sep;621:119-130. doi: 10.1016/j.jcis.2022.04.057. Epub 2022 Apr 15.

Abstract

To improve gas sensing performance of SnO sensor, a heterostructure constructed by SnO and SnSe is designed and synthesized via hydrothermal method and post thermal oxidation treatment. The obtained SnSe/SnO composite nanoparticles demonstrate a special core-shell structure with SnO nanograins distributed in the shell and mixed SnSe and SnO nanograins in the core. Owning to the promoted charge transfer effect invited by SnSe, the sensor based on SnSe/SnO composite nanoparticles exhibit expressively enhanced acetone sensing performance compared to the pristine SnO sensor. At the working temperature of 300 °C, the SnSe/SnO composite sensor with optimized composition exhibits superior sensing property towards acetone, including high response (10.77-100 ppm), low theoretical limit of detection (0.354 ppm), high selectivity and good reproducibility. Moreover, the sensor shows a satisfactory sensing performance in trace acetone gas detection under high humidity condition (relative humidity: 70-90%), making it a promising candidate to constructing exhaled breath sensors for acetone detection.

摘要

为了提高SnO传感器的气敏性能,通过水热法和后续热氧化处理设计并合成了一种由SnO和SnSe构建的异质结构。所制备的SnSe/SnO复合纳米颗粒呈现出一种特殊的核壳结构,其中SnO纳米颗粒分布在壳层,而核层则是SnSe和SnO纳米颗粒的混合物。由于SnSe引发的电荷转移效应增强,基于SnSe/SnO复合纳米颗粒的传感器相较于原始SnO传感器,其丙酮气敏性能显著增强。在300℃的工作温度下,具有优化组成的SnSe/SnO复合传感器对丙酮表现出优异的传感性能,包括高响应(10.77 - 100 ppm)、低理论检测限(0.354 ppm)、高选择性和良好的重现性。此外,该传感器在高湿度条件(相对湿度:70 - 90%)下对痕量丙酮气体检测也表现出令人满意的传感性能,使其成为构建用于丙酮检测的呼气传感器的有潜力候选材料。

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