Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, Beijing 100124, China.
Int J Mol Sci. 2022 Apr 11;23(8):4206. doi: 10.3390/ijms23084206.
Here, we report a design strategy for constructing supramolecular organic frameworks by introducing H-pyrazole groups to aromatic cores as non-coplanar molecules to form diverse supramolecular assemblies through multiple H-pyrazole [N-H···N] hydrogen bonds as well as other weak interactions. The new supramolecular organic frameworks displayed interesting crystallization-induced emission (CIE) behavior.
在这里，我们报告了一种通过在芳核中引入 H-吡唑基团作为非共面分子来构建超分子有机框架的设计策略，通过多个 H-吡唑 [N-H···N] 氢键以及其他弱相互作用形成多种超分子组装体。新的超分子有机框架表现出有趣的结晶诱导发光（CIE）行为。
