Ultrasensitive and Recyclable Multifunctional Superhydrophobic Sensor Membrane for Underwater Applications, Weather Monitoring, and Wastewater Treatment.

Although flexible sensors have attracted considerable attention in emerging fields, including wearable electronics and soft robotics, their stability must be considered in practical applications, especially the effects of external factors on the sensing performance. Herein, a recyclable flexible sensor with superhydrophobicity and a highly sensitive strain response was developed by combining electrospinning and ultrasonication anchoring techniques. The constructed hierarchical network structure is composed of the fluorine-free superhydrophobic multiwalled carbon nanotubes and a porous elastomer membrane substrate reinforced by nanoparticles. The obtained sensor exhibited exceptional strain-sensing performance in terms of ultrahigh sensitivity (maximum gauge factor of 12 172.46), a fast response time of 80 ms, and excellent durability (10 000 cycles). Based on these outstanding merits, the strain sensor can detect various human motions without being interfered with by harsh environments. Moreover, superhydrophobic membranes can be combined with electronic devices for weather monitoring and underwater sensing. Noteworthily, damaged sensors can be quickly dissolved by a small amount of cyclohexane, enabling material recovery. The recyclable multifunctional membranes could reduce the potential pollution to the environment and show highly promising applications in complex environments.