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用于光催化降解罗丹明B染料的界面富集高度交错层状MoS/NiS纳米复合材料

Interface enriched highly interlaced layered MoS/NiS nanocomposites for the photocatalytic degradation of rhodamine B dye.

作者信息

Harish S, Bharathi P, Prasad Prachi, Ramesh R, Ponnusamy S, Shimomura M, Archana J, Navaneethan M

机构信息

Functional Materials and Energy Devices Laboratory, Department of Physics and Nanotechnology, SRM Institute of Science and Technology Kattankulathur 603 203 India

Department of Physics, Periyar University Salem 636011 India.

出版信息

RSC Adv. 2021 May 27;11(31):19283-19293. doi: 10.1039/d1ra01941d. eCollection 2021 May 24.

Abstract

In the past few decades, air and water pollution by organic dyes has become a serious concern due to their high toxicity. Removal of these organic dyes from polluted water bodies is a serious environmental concern and the development of new advanced photocatalytic materials for decomposing organic dyes can be a good solution. In this work, layered molybdenum disulfide/nickel disulfide (MoS/NiS) nanocomposites with various NiS content was synthesized by a one-step hydrothermal method using citric acid as a reducing agent. The X-ray diffraction pattern shows the hexagonal and cubical crystal structure of MoS and NiS, respectively. Morphological analysis confirms the formation of MoS/NiS nanosheets. The elemental composition of the samples was carried out by XPS, which shows a significant interaction between NiS and MoS. The photocatalytic performance of MoS/NiS nanocomposites was studied by the degradation of rhodamine B (RhB). Ni-4 sample shows higher photocatalytic activity with a maximum degradation of 90.61% under visible light irradiation for 32 min.

摘要

在过去几十年里,有机染料造成的空气和水污染因其高毒性已成为一个严重问题。从受污染水体中去除这些有机染料是一个严峻的环境问题,开发用于分解有机染料的新型先进光催化材料可能是一个很好的解决方案。在这项工作中,以柠檬酸作为还原剂,通过一步水热法合成了具有不同NiS含量的层状二硫化钼/二硫化镍(MoS₂/NiS)纳米复合材料。X射线衍射图谱分别显示了MoS₂和NiS的六方和立方晶体结构。形态分析证实了MoS₂/NiS纳米片的形成。通过X射线光电子能谱对样品的元素组成进行了分析,结果表明NiS和MoS₂之间存在显著相互作用。通过罗丹明B(RhB)的降解研究了MoS₂/NiS纳米复合材料的光催化性能。Ni-4样品表现出较高的光催化活性,在可见光照射32分钟下最大降解率为90.61%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f105/9033572/23b97c51c4f7/d1ra01941d-f1.jpg

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