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用于纳米塑料修复的基于碳硅石的移动床3D打印水处理系统的开发。

Development of a schwarzite-based moving bed 3D printed water treatment system for nanoplastic remediation.

作者信息

Gupta Bramha, Ambekar Rushikesh S, Tromer Raphael M, Ghosal Partha Sarathi, Sinha Rupal, Majumder Abhradeep, Kumbhakar Partha, Ajayan P M, Galvao Douglas S, Gupta Ashok Kumar, Tiwary Chandra Sekhar

机构信息

School of Water Resources, Indian Institute of Technology Kharagpur Kharagpur 721302 India.

Metallurgical and Materials Engineering, Indian Institute of Technology Kharagpur Kharagpur 721302 India

出版信息

RSC Adv. 2021 Jun 1;11(32):19788-19796. doi: 10.1039/d1ra03097c. eCollection 2021 May 27.

DOI:10.1039/d1ra03097c
PMID:35479224
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9033670/
Abstract

The impact of micro and nanoplastic debris on our aquatic ecosystem is among the most prominent environmental challenges we face today. In addition, nanoplastics create significant concern for environmentalists because of their toxicity and difficulty in separation and removal. Here we report the development of a 3D printed moving bed water filter (M-3DPWF), which can perform as an efficient nanoplastic scavenger. The enhanced separation of the nanoplastics happens due to the creation of a charged filter material that traps the more surface charged nanoparticles selectively. Synthetic contaminated water from polycarbonate waste has been tested with the filter, and enhanced nanoplastic removal has been achieved. The proposed filtration mechanism of surface-charge based water cleaning is further validated using density function theory (semi-empirical) based simulation. The filter has also shown good structural and mechanical stability in both static and dynamic water conditions. The field suitability of the novel treatment system has also been confirmed using water from various sources, such as sea, river, and pond. Our results suggest that the newly developed water filter can be used for the removal of floating nanoparticles in water as a robust advanced treatment system.

摘要

微塑料和纳米塑料碎片对我们水生生态系统的影响是我们当今面临的最突出的环境挑战之一。此外,纳米塑料因其毒性以及分离和去除的困难而引起环保主义者的重大关注。在此,我们报告了一种3D打印移动床水过滤器(M-3DPWF)的开发,它可以作为一种高效的纳米塑料清除剂。纳米塑料分离效果的增强是由于形成了一种带电过滤材料,该材料能选择性地捕获表面电荷更多的纳米颗粒。已使用该过滤器对来自聚碳酸酯废料的合成污染水进行了测试,并实现了纳米塑料去除率的提高。基于密度泛函理论(半经验)的模拟进一步验证了所提出的基于表面电荷的水净化过滤机制。该过滤器在静态和动态水条件下均表现出良好的结构和机械稳定性。使用来自海洋、河流和池塘等各种水源的水也证实了这种新型处理系统的现场适用性。我们的结果表明,新开发的水过滤器可作为一种强大的深度处理系统用于去除水中的漂浮纳米颗粒。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/58a8920d2198/d1ra03097c-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/5593aa453e5b/d1ra03097c-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/495c5bcdb3ba/d1ra03097c-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/e687a82bd95e/d1ra03097c-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/56c368b437b4/d1ra03097c-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/58a8920d2198/d1ra03097c-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/5593aa453e5b/d1ra03097c-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/495c5bcdb3ba/d1ra03097c-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/e687a82bd95e/d1ra03097c-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/56c368b437b4/d1ra03097c-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f68d/9033670/58a8920d2198/d1ra03097c-f5.jpg

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