Wei Bo, Wei Tiantian, Xie Caifeng, Li Kai, Hang Fangxue
School of Light Industrial and Food Engineering, Guangxi University Nanning 530004 China
Provincial and Ministerial Collaborative Innovation Center for Industry Nanning 530004 China.
RSC Adv. 2021 Aug 19;11(45):28138-28147. doi: 10.1039/d1ra04143f. eCollection 2021 Aug 16.
We present a simple, low-cost method for producing activated-carbon materials from sugarcane tips (ST) two-step pre-carbonization and KOH activation treatment. After optimizing the amount of KOH, the resulting ST-derived activated carbon prepared with a KOH to PC-ST mass ratio of 2 (ACST-2) contained 17.04 wt% oxygen and had a large surface area of 1206.85 m g, which could be attributed to the large number of micropores in ACST-2. In a three-electrode system, the ACST-2 electrode exhibited a high specific capacitance of 259 F g at 0.5 A g and good rate capability with 82.66% retention from 0.5 to 10 A g. In addition, it displayed a high capacitance retention of 89.6% after 5000 cycles at a current density of 3 A g, demonstrating excellent cycling stability. Furthermore, the ACST-2//ACST-2 symmetric supercapacitor could realize a high specific energy density of 7.93 W h kg at a specific power density of 100 W kg in 6 M KOH electrolyte. These results demonstrate that sugarcane tips, which are inexpensive and easily accessible agricultural waste, can be used to create a novel biomass precursor for the production of low-cost activated carbon materials for high-performance supercapacitors.
我们提出了一种简单、低成本的方法,通过两步预碳化和KOH活化处理,从甘蔗梢(ST)制备活性炭材料。优化KOH用量后,以KOH与预碳化甘蔗梢(PC-ST)质量比为2制备的ST衍生活性炭(ACST-2)含有17.04 wt%的氧,表面积大,为1206.85 m²/g,这可归因于ACST-2中大量的微孔。在三电极系统中,ACST-2电极在0.5 A/g时表现出259 F/g的高比电容,倍率性能良好,在0.5至10 A/g之间保持率为82.66%。此外,在3 A/g的电流密度下循环5000次后,其电容保持率高达89.6%,显示出优异的循环稳定性。此外,ACST-2//ACST-2对称超级电容器在6 M KOH电解液中,在100 W/kg的比功率密度下可实现7.93 W h/kg的高比能量密度。这些结果表明,甘蔗梢作为廉价且易于获取的农业废弃物,可用于制造一种新型生物质前驱体,以生产用于高性能超级电容器的低成本活性炭材料。