Li Zhaojin, Liu Qian, Sun Lizhi, Li Ning, Wang Xiaofeng, Wang Qiujun, Zhang Di, Wang Bo
Hebei Key Laboratory of Flexible Functional Materials, School of Materials Science and Engineering, Hebei University of Science and Technology Hebei 050018 China
Shenzhou Engineering Plastics Company Limited Boling East Road 106, Shenzhou Economic Development Zone Hebei 053800 China.
RSC Adv. 2021 Oct 8;11(53):33208-33218. doi: 10.1039/d1ra06154b.
It is a considerable challenge to produce a supercapacitor with inexpensive raw materials and employ a simple process to obtain carbon materials with a high specific surface area, rich pore structure, and appropriate doping of heterogeneous elements. In the current study, yam waste-derived porous carbon was synthesized for the first time by a two-step carbonization and KOH chemical activation process. An ultra-high specific surface area of 2382 m g with a pore volume of 1.11 cm g and simultaneous co-doping of O-N was achieved for the optimized sample. Because of these distinct features, the optimized material exhibits a high gravimetric capacitance of 423.23 F g at 0.5 A g with an impressive rate capability at 10 A g, and prominent cycling durability with a capacity retention of 96.4% at a high current density of 10 A g after 10 000 cycles in 6 M KOH in a three-electrode system. Moreover, in 6 M KOH electrolyte, the assembled symmetrical supercapacitor provides a large of 387.3 F g at 0.5 A g. It also presents high specific energy of 34.6 W h kg when the specific power is 200.1 W kg and a praiseworthy specific energy of 8.3 W h kg when the specific power is 4000.0 W kg in 1 M NaSO electrolyte. Thus, this study provides reference and guidance for developing high-performance electrode materials for supercapacitors.
使用廉价原材料生产超级电容器,并采用简单工艺获得具有高比表面积、丰富孔结构和适当异质元素掺杂的碳材料是一项相当大的挑战。在当前研究中,首次通过两步碳化和KOH化学活化工艺合成了山药废料衍生的多孔碳。优化后的样品实现了2382 m²/g的超高比表面积、1.11 cm³/g的孔体积以及O-N的同时共掺杂。由于这些独特的特性,优化后的材料在0.5 A/g时表现出423.23 F/g的高比电容,在10 A/g时具有令人印象深刻的倍率性能,并且在三电极体系中于6 M KOH中10000次循环后,在10 A/g的高电流密度下具有96.4%的容量保持率,展现出卓越的循环耐久性。此外,在6 M KOH电解液中,组装的对称超级电容器在0.5 A/g时提供387.3 F/g的高比电容。在1 M Na₂SO₄电解液中,当比功率为200.1 W/kg时,其还具有34.6 W h/kg的高比能量,当比功率为4000.0 W/kg时,具有8.3 W h/kg的可观比能量。因此,本研究为开发高性能超级电容器电极材料提供了参考和指导。