Study of mid-latitude retrieval XCO greenhouse gas: Validation of satellite-based shortwave infrared spectroscopy with ground-based TCCON observations.

Carbon dioxide (CO) is a major greenhouse gas. This study investigated the performance of three common algorithms, namely NIES, ACOS, and Remo Tec (SRFP). These algorithms were compared using GOSAT observation satellite data with reference data obtained from TCCON during the period 2009-2021. According to statistical evaluation, the SRFP and NIES algorithms achieved the lowest and highest correlation values of the 13 year (2009_2021) average of all sites, respectively. The average bias error values of NIES and ACOS was estimated to be less than that of SRFP approximately 0.5 ppm, while the bias within SRFP was of about 2 ppm. Comparing the RMSE and CRMS error values showed that the highest and lowest error values were related to the SRFP and NIES algorithms respectively, which were 0.37-1.67 and ppm 1.46-7.9. The researchers also compared them with monthly time changes based on ground measurements, and observed a time series of CO concentration changes that well matched the trend of gas concentration values at ground stations obtained by NIES algorithm. The results showed that in most cases NIES was an effective algorithm to retrieve carbon dioxide gas concentrations, allowing the researchers to identify the main sources of greenhouse gas emissions in different areas. The clustering result in the study area showed that the continental CO columnar concentration has a specific seasonal cycle, with the maximum and minimum values appearing in winter-early spring and spring-late summer, respectively. In conclusion, cluster analysis can classify the surface CO column concentration values and determine the spatial distribution pattern of CO.