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碳量子点上的氨基酸功能化策略意味着多种应用吗?全面综述。

Do amino acid functionalization stratagems on carbonaceous quantum dots imply multiple applications? A comprehensive review.

作者信息

Ravi Pavithra V, Subramaniyam Vinodhini, Pattabiraman Ajay, Pichumani Moorthi

机构信息

Department of Nanoscience and Technology, Sri Ramakrishna Engineering College Coimbatore 641 022 Tamilnadu India

Government Primary Health Center Anaikatti Coimbatore 641 108 Tamilnadu India.

出版信息

RSC Adv. 2021 Oct 29;11(55):35028-35045. doi: 10.1039/d1ra05571b. eCollection 2021 Oct 25.

DOI:10.1039/d1ra05571b
PMID:35494767
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9043014/
Abstract

Amino acids are the noteworthy entity among biological molecules with diverse properties such as zwitterionic and amphoteric. Functionalizing carbon-based quantum dots using amino acids might be used for the extreme enhancement of electronic and optical properties of quantum dots and improve the performance of the resultant amino acid-functionalized quantum dots. The amino acid-functionalized quantum dots are highly soluble, sustainable, and biocompatible with virtuous optical and electrical performance, which makes them potential and suitable candidates for fabricating optoelectronic devices. The tenacity of using amino acids as functional groups to functionalize quantum dots and their novel properties are conferred to attain their multiple applications. The goal of this review is to provide the choices of amino acids based on the desired applications and a variety of functionalization techniques to make them a noteworthy material for future applications. The method of one-step and two-step functionalization strategies along with the properties of the resultant functionalized quantum dots and their plausible applications and future scope of the material are highlighted. Amidation is the basic principle behind the functionalization of quantum dots with amino acids. This review would be an exciting prospect to explore the pathways of the possible applications in different domains, in which the amino acid-functionalized quantum dots have not yet been explored. Further, this review article helps in pitching a variety of prominent applications right from sensors to energy storage systems either using the optical property or electronic property of amino acid-functionalized quantum dots.

摘要

氨基酸是生物分子中值得关注的实体,具有多种特性,如两性离子和两性性质。使用氨基酸对碳基量子点进行功能化,可能用于极大增强量子点的电子和光学性质,并改善所得氨基酸功能化量子点的性能。氨基酸功能化量子点具有高度溶解性、可持续性且生物相容性良好,同时具备优异的光学和电学性能,这使其成为制造光电器件的潜在且合适的候选材料。使用氨基酸作为官能团对量子点进行功能化的坚韧性以及它们的新特性,被赋予以实现其多种应用。本综述的目的是根据所需应用提供氨基酸的选择以及各种功能化技术,使其成为未来应用中值得关注的材料。重点介绍了一步法和两步法功能化策略,以及所得功能化量子点的性质、它们可能的应用和该材料的未来前景。酰胺化是用氨基酸对量子点进行功能化的基本原理。本综述将是一个令人兴奋的前景,可探索在不同领域中可能的应用途径,其中氨基酸功能化量子点尚未得到探索。此外,这篇综述文章有助于提出从传感器到储能系统等各种突出应用,这些应用要么利用氨基酸功能化量子点的光学性质,要么利用其电子性质。

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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8776/9043014/810542591c7a/d1ra05571b-f5.jpg
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