基于铽/铕的四核倍半硅氧烷笼中的温度传感及可调发射
Temperature sensing in Tb/Eu-based tetranuclear silsesquioxane cages with tunable emission.
作者信息
Nigoghossian Karina, Kulakova Alena N, Félix Gautier, Khrustalev Victor N, Shubina Elena S, Long Jérôme, Guari Yannick, Sene Saad, Carlos Luís D, Bilyachenko Alexey N, Larionova Joulia
机构信息
ICGM, Univ. Montpellier, CNRS, ENSCM Montpellier France
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences Vavilova str., 28 Moscow 119991 Russia
出版信息
RSC Adv. 2021 Oct 27;11(55):34735-34741. doi: 10.1039/d1ra06755a. eCollection 2021 Oct 25.
New luminescent cage-like tetranuclear silsesquioxanes [NEt][(PhSiO)(TbEu)(NO)(OH)(EtOH)(HO)]·4(EtOH) (1) and [NEt][(PhSiO)(TbEu)(NO)(EtOH)(MeCN)]·4(MeCN) (2) present a tunable thermosensitive Tb-to-Eu energy transfer driven by Tb and Eu emission and may be used as temperature sensors operating in the range 41-100 °C with excellent linearity ( = 0.9990) and repeatability (>95%). The thermometer performance was evidenced by the maximum relative sensitivity of 0.63% °C achieved at 68 °C.
新型发光笼状四核倍半硅氧烷[NEt₄][(PhSiO₁.₅)₈(Tb₂Eu₂)(NO₃)₂(OH)₂(EtOH)₂(H₂O)₂]·4(EtOH) (1)和[NEt₄][(PhSiO₁.₅)₈(Tb₂Eu₂)(NO₃)₂(EtOH)₂(MeCN)₂]·4(MeCN) (2)呈现出由Tb和Eu发射驱动的可调谐热敏Tb到Eu能量转移，并且可用作在41 - 100 °C范围内运行的温度传感器，具有出色的线性度(相关系数 = 0.9990)和可重复性(>95%)。在68 °C时实现的最大相对灵敏度为0.63% °C，证明了其温度计性能。
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