• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

使用磁性聚三嗪 - 苯磺酰胺 - SOH合成杯间苯二酚芳烃。

Synthesis of calixresorcarenes using magnetic poly triazine-benzene sulfonamide-SOH.

作者信息

Gharehkhani Alireza, Ghorbani-Vaghei Ramin, Alavinia Sedigheh

机构信息

Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University Zip Code 65174 Hamedan Iran

出版信息

RSC Adv. 2021 Nov 22;11(59):37514-37527. doi: 10.1039/d1ra07393a. eCollection 2021 Nov 17.

DOI:10.1039/d1ra07393a
PMID:35496418
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9043749/
Abstract

The purpose of this work is to develop a magnetically recyclable immobilized base catalyst for the green synthesis of calixresorcarenes. To achieve this, poly triazine-benzene sulfonamide (PTBSA) has been coated on magnetic FeO nanoparticles and subsequently chlorosulfonic acid has been supported to obtain FeO@PTBSA-SOH. The structure of nano-FeO@PTBSA-SOH was characterized by TEM, XRD, FT-IR, VSM, WDX, EDX, TGA/DSC and FE-SEM. The catalytic efficiency of this catalyst was also investigated in the synthesis of novel calixresorcarene derivatives. The advantages of heterogeneous nature, catalytic activity and the recyclability of the polymer support were also strengthened by advanced surface treatment. These key factors (basic sites, acidic sites and heterogeneity) play essential roles in the catalyst performance. This procedure has some advantages such as short reaction time, clean and fast work-up and easy separation of the catalyst by an external magnet.

摘要

这项工作的目的是开发一种用于杯芳烃绿色合成的磁性可回收固定化碱催化剂。为此，聚三嗪 - 苯磺酰胺（PTBSA）已被包覆在磁性FeO纳米颗粒上，随后负载氯磺酸以获得FeO@PTBSA - SOH。通过透射电子显微镜（TEM）、X射线衍射（XRD）、傅里叶变换红外光谱（FT - IR）、振动样品磁强计（VSM）、波长色散X射线光谱仪（WDX）、能量散射X射线光谱仪（EDX）、热重/差示扫描量热仪（TGA/DSC）和场发射扫描电子显微镜（FE - SEM）对纳米FeO@PTBSA - SOH的结构进行了表征。还研究了该催化剂在新型杯芳烃衍生物合成中的催化效率。聚合物载体的多相性质、催化活性和可回收性等优点也通过先进的表面处理得到了强化。这些关键因素（碱性位点、酸性位点和多相性）在催化剂性能中起着至关重要的作用。该方法具有一些优点，如反应时间短、后处理干净快速以及通过外部磁铁易于分离催化剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/cd4f50aaa2d6/d1ra07393a-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/312faae154b1/d1ra07393a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/cd7184456a44/d1ra07393a-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/725d1c8ac989/d1ra07393a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/8d536e26b4e1/d1ra07393a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/d75a684a7dec/d1ra07393a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/0f511b6089d1/d1ra07393a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/34957e90bac4/d1ra07393a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/54854208eca0/d1ra07393a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/f06c88e60b17/d1ra07393a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/7a7cb83b6f15/d1ra07393a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/4b9f57444c4c/d1ra07393a-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/90aa964d5668/d1ra07393a-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/f20ca950d3a1/d1ra07393a-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/63e259613c4a/d1ra07393a-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/cd4f50aaa2d6/d1ra07393a-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/312faae154b1/d1ra07393a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/cd7184456a44/d1ra07393a-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/725d1c8ac989/d1ra07393a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/8d536e26b4e1/d1ra07393a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/d75a684a7dec/d1ra07393a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/0f511b6089d1/d1ra07393a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/34957e90bac4/d1ra07393a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/54854208eca0/d1ra07393a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/f06c88e60b17/d1ra07393a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/7a7cb83b6f15/d1ra07393a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/4b9f57444c4c/d1ra07393a-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/90aa964d5668/d1ra07393a-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/f20ca950d3a1/d1ra07393a-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/63e259613c4a/d1ra07393a-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bc7/9043749/cd4f50aaa2d6/d1ra07393a-f12.jpg

相似文献

1
Synthesis of calixresorcarenes using magnetic poly triazine-benzene sulfonamide-SOH.使用磁性聚三嗪 - 苯磺酰胺 - SOH合成杯间苯二酚芳烃。
RSC Adv. 2021 Nov 22;11(59):37514-37527. doi: 10.1039/d1ra07393a. eCollection 2021 Nov 17.
2
Ionophore silica-coated magnetite nanoparticles as a recyclable heterogeneous catalyst for one-pot green synthesis of 2,4,5-trisubstituted imidazoles.离子载体二氧化硅包覆的磁铁矿纳米颗粒作为一种可循环利用的多相催化剂用于一锅法绿色合成2,4,5-三取代咪唑。
Dalton Trans. 2016 Jan 21;45(3):1243-53. doi: 10.1039/c5dt03488d.
3
An efficient and green one-pot synthesis of tetrahydrobenzo[a]xanthenes, 1,8-dioxo-octahydroxanthenes and dibenzo[a,j]xanthenes by FeO@Agar-Ag as nanocatalyst.FeO@Agar-Ag 纳米催化剂高效绿色一锅法合成四氢苯并[a]呫吨、1,8-二氧代-氧杂环庚并[a]呫吨和二苯并[a,j]呫吨
Mol Divers. 2022 Oct;26(5):2745-2759. doi: 10.1007/s11030-021-10368-3. Epub 2022 Jan 29.
4
Chlorosulfonic acid coated on porous organic polymer as a bifunctional catalyst for the one-pot three-component synthesis of 1,8-naphthyridines.负载于多孔有机聚合物上的氯磺酸作为双功能催化剂用于一锅法三组分合成1,8-萘啶。
RSC Adv. 2022 Sep 28;12(43):27723-27735. doi: 10.1039/d2ra05070f.
5
Diphenyl diselenide immobilized on magnetic nanoparticles: A novel and retrievable heterogeneous catalyst in the oxidation of aldehydes under mild and green conditions.二苯二硒醚固载在磁性纳米颗粒上：一种新型且可回收的多相催化剂，用于在温和绿色条件下氧化醛。
J Colloid Interface Sci. 2018 Jan 1;509:485-494. doi: 10.1016/j.jcis.2017.09.034. Epub 2017 Sep 8.
6
Ni(ii) immobilized on poly(guanidine-triazine-sulfonamide) (PGTSA/Ni): a mesoporous nanocatalyst for synthesis of imines.负载于聚（胍 - 三嗪 - 磺酰胺）（PGTSA/Ni）上的镍（II）：一种用于合成亚胺的介孔纳米催化剂。
RSC Adv. 2022 Nov 30;12(53):34425-34437. doi: 10.1039/d2ra06196a. eCollection 2022 Nov 29.
7
Preparation of core/shell nanostructure Fe(3)O(4)@PEG400-SO(3)H as heterogeneous and magnetically recyclable nanocatalyst for one-pot synthesis of substituted pyrroles by Paal-Knorr reaction at room temperature.核壳纳米结构Fe(3)O(4)@PEG400-SO(3)H的制备及其作为多相可磁回收纳米催化剂用于室温下通过Paal-Knorr反应一锅法合成取代吡咯
J Colloid Interface Sci. 2017 Jun 15;496:177-187. doi: 10.1016/j.jcis.2017.02.023. Epub 2017 Feb 13.
8
Supported l-tryptophan on FeO@SiO as an efficient and magnetically separable catalyst for one-pot construction of spiro[indene-2,2'-naphthalene]-4'-carbonitrile derivatives.负载于FeO@SiO上的L-色氨酸作为一种高效且可磁分离的催化剂用于一锅法构建螺[茚-2,2'-萘]-4'-甲腈衍生物。
RSC Adv. 2022 Jan 5;12(3):1319-1330. doi: 10.1039/d1ra07654j.
9
Green synthesis of quinazoline derivatives using a novel recyclable nano-catalyst of magnetic modified graphene oxide supported with copper.使用负载铜的磁性修饰氧化石墨烯新型可回收纳米催化剂绿色合成喹唑啉衍生物
Sci Rep. 2023 Nov 28;13(1):20958. doi: 10.1038/s41598-023-48120-6.
10
A novel superparamagnetic powerful guanidine-functionalized γ-FeO based sulfonic acid recyclable and efficient heterogeneous catalyst for microwave-assisted rapid synthesis of quinazolin-4(3)-one derivatives in Green media.一种新型超顺磁性的、功能化胍基的γ-FeO基磺酸可回收高效多相催化剂，用于在绿色介质中微波辅助快速合成喹唑啉-4(3)-酮衍生物。
RSC Adv. 2021 Sep 7;11(48):29948-29959. doi: 10.1039/d1ra05560g. eCollection 2021 Sep 6.

引用本文的文献

1
Pd NPs decorated on crosslinked sodium alginate modified iron-based metal-organic framework Fe(BTC) as a green multifunctional catalyst for the oxidative amidation.负载于交联海藻酸钠修饰的铁基金属有机框架Fe(BTC)上的钯纳米颗粒作为氧化酰胺化反应的绿色多功能催化剂。
Nanoscale Adv. 2024 May 20;6(14):3612-3623. doi: 10.1039/d4na00151f. eCollection 2024 Jul 9.
2
Green synthesis of thiourea derivatives from nitrobenzenes using Ni nanoparticles immobilized on triazine-aminopyridine-modified MIL-101(Cr) MOF.使用固定在三嗪-氨基吡啶修饰的MIL-101(Cr)金属有机框架上的镍纳米颗粒从硝基苯绿色合成硫脲衍生物。
Sci Rep. 2023 Aug 10;13(1):12964. doi: 10.1038/s41598-023-40190-w.
3

本文引用的文献

1
The preparation, characterization and catalytic activity of Ni NPs supported on porous alginate--poly(-styrene sulfonamide--acrylamide).负载于多孔海藻酸钠-聚（苯乙烯磺酰胺-丙烯酰胺）上的镍纳米颗粒的制备、表征及催化活性
RSC Adv. 2021 Sep 6;11(47):29728-29740. doi: 10.1039/d1ra04022g. eCollection 2021 Sep 1.
2
CuI nanoparticles supported on a novel polymer-layered double hydroxide nanocomposite: an efficient heterogeneous nanocatalyst for the synthesis of bis--arylsulfonamides.负载于新型聚合物层状双氢氧化物纳米复合材料上的碘化亚铜纳米颗粒：一种用于合成双芳基磺酰胺的高效多相纳米催化剂。
RSC Adv. 2021 May 26;11(31):19147-19157. doi: 10.1039/d1ra02086b. eCollection 2021 May 24.
3
Chlorosulfonic acid coated on porous organic polymer as a bifunctional catalyst for the one-pot three-component synthesis of 1,8-naphthyridines.
负载于多孔有机聚合物上的氯磺酸作为双功能催化剂用于一锅法三组分合成1,8-萘啶。
RSC Adv. 2022 Sep 28;12(43):27723-27735. doi: 10.1039/d2ra05070f.
Green synthesis of Cu-doped ZnO nanoparticles and its application for the photocatalytic degradation of hazardous organic pollutants.
绿色合成掺铜氧化锌纳米粒子及其在光催化降解危险有机污染物中的应用。
Chemosphere. 2022 Jan;287(Pt 2):132081. doi: 10.1016/j.chemosphere.2021.132081. Epub 2021 Aug 31.
4
Azo-methoxy-calix[4]arene complexes with metal cations for chemical sensor applications: Characterization, QTAIM analyses and dispersion-corrected DFT- computations.偕氧甲氧基杯[4]芳烃金属配合物用于化学传感器的应用：特性描述、QTAIM 分析和经色散校正的 DFT 计算。
Spectrochim Acta A Mol Biomol Spectrosc. 2022 Jan 5;264:120242. doi: 10.1016/j.saa.2021.120242. Epub 2021 Jul 30.
5
Data on the fabrication of hybrid calix [4]arene-modified natural bentonite clay for efficient selective removal of toxic metals from wastewater at room temperature.关于制备杂化杯[4]芳烃改性天然膨润土粘土以在室温下有效选择性去除废水中有毒金属的数据。
Data Brief. 2021 Jan 30;35:106799. doi: 10.1016/j.dib.2021.106799. eCollection 2021 Apr.
6
Calix[4]arene tetracarboxylic acid-treated lipase immobilized onto metal-organic framework: Biocatalyst for ester hydrolysis and kinetic resolution.杯[4]芳烃四羧酸处理的固定化脂肪酶：用于酯水解和动力学拆分的生物催化剂。
Int J Biol Macromol. 2021 Apr 1;175:79-86. doi: 10.1016/j.ijbiomac.2021.02.003. Epub 2021 Feb 4.
7
An overview on recent advances in the synthesis of sulfonated organic materials, sulfonated silica materials, and sulfonated carbon materials and their catalytic applications in chemical processes.磺化有机材料、磺化硅材料和磺化碳材料的合成及其在化学过程中的催化应用的最新进展综述。
Beilstein J Org Chem. 2018 Nov 1;14:2745-2770. doi: 10.3762/bjoc.14.253. eCollection 2018.
8
Development of Sulfonic-Acid-Functionalized Mesoporous Materials: Synthesis and Catalytic Applications.磺酸功能化介孔材料的开发：合成与催化应用。
Chemistry. 2019 Feb 1;25(7):1614-1635. doi: 10.1002/chem.201802183. Epub 2018 Nov 20.
9
Calixdrugs: calixarene-based clusters of established therapeutic drug agents.杯芳烃药物：基于杯芳烃的已确立治疗药物的簇合物。
Mol Divers. 2016 Aug;20(3):781-7. doi: 10.1007/s11030-016-9667-x. Epub 2016 Mar 26.
10
Synthesis, luminescence, and electrochemical studies of a new series of octanuclear ruthenium(II) complexes of tolylterpyridine appended calixresorcarenes.新型含对甲苯基吡啶 appended 杯芳烃的八核钌(II)配合物的合成、发光和电化学研究。
Dalton Trans. 2015 Sep 7;44(33):14813-22. doi: 10.1039/c5dt02363g.