Green synthesis of thiourea derivatives from nitrobenzenes using Ni nanoparticles immobilized on triazine-aminopyridine-modified MIL-101(Cr) MOF.

Nanohybrid metal-organic frameworks (MOF) have recently been considered next-generation catalysts regarding their unique features like large surface-to-volume ratio, tailorable geometry, uniform pore sizes, and homogeneous distribution of active sites. In this report, we address the triazine-aminopyridine-modified 3D Cr-centred MOF MIL-101(Cr)-NH following a post-synthetic modification approach. The excellent chelating ability of triazine-aminopyridine was applied to immobilize Ni ions over the host matrix MOF. The as-synthesized material was physicochemically characterized using various analytical techniques like FT-IR, electron microscopy, EDS, elemental mapping, XRD, and ICP-OES. Subsequently, the material has been catalytically employed in synthesizing new thiourea derivatives by reacting to nitrobenzene derivatives and phenyl isocyanate. The catalyst was isolated by centrifugation and recycled in 6 consecutive runs without momentous loss of its reactivity.