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磺酸功能化介孔材料的开发:合成与催化应用。

Development of Sulfonic-Acid-Functionalized Mesoporous Materials: Synthesis and Catalytic Applications.

机构信息

International Center for Materials Nanoarchitechtonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan.

Key Laboratory of Sensor Analysis of Tumor Marker (Ministry of, Education), Shandong Key Laboratory of Biochemical Analysis, Key Laboratory of, Analytical Chemistry for Life Science in Universities of, Shandong, College of Chemistry and Molecular Engineering Qingdao University of Science and Technology, Qingdao, 266042, P.R. China.

出版信息

Chemistry. 2019 Feb 1;25(7):1614-1635. doi: 10.1002/chem.201802183. Epub 2018 Nov 20.

Abstract

Sulfonic acid based mesostructures (SAMs) have been developed in recent years and have important catalytic applications. The primary applications of these materials are in various organic synthesis reactions, such as multicomponent reactions, carbon-carbon bond couplings, protection reactions, and Fries and Beckman rearrangements. This review aims to provide an overview of the recent developments in the field of SAMs with a particular emphasis on the reaction scope and advantages of heterogeneous solid acid catalysts.

摘要

近年来,基于磺酸的介孔结构(SAMs)得到了发展,并在催化领域具有重要的应用。这些材料的主要应用是在各种有机合成反应中,如多组分反应、碳-碳键偶联反应、保护反应和 Frie 和 Beckman 重排反应。本综述旨在概述 SAMs 领域的最新发展,特别强调了多相固体酸催化剂的反应范围和优势。

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