School of Pharmacy, Henan University of Chinese Medicine, Zhengzhou, 450046, China.
Academy of Chinese Medical Sciences, Henan University of Chinese Medicine, Zhengzhou, 450046, China.
Org Biomol Chem. 2022 May 18;20(19):3902-3906. doi: 10.1039/d2ob00557c.
A photoexcited sulfenylation of C(sp)-H bonds in amides is developed for the synthesis of sulfenyl amides using thiosulfonates as a sulfur source. In the presence of easily available and inexpensive Na-eosin Y, TBHP and KCO, various sulfenyl amides can be obtained under the irradiation of blue light at room temperature.
发展了一种酰胺中 C(sp 3 )-H 键的光激发硫代磺酰化反应，使用硫代磺酸盐作为硫源合成了硫代酰胺。在易得且廉价的曙红 Y-Na、TBHP 和 KCO 的存在下，各种硫代酰胺可以在蓝光照射下于室温下得到。
