利用硫代硫酸盐实现酰胺中 C(sp)-H 键的光激发硫代磺酰化反应。
Photoexcited sulfenylation of C(sp)-H bonds in amides using thiosulfonates.
机构信息
School of Pharmacy, Henan University of Chinese Medicine, Zhengzhou, 450046, China.
Academy of Chinese Medical Sciences, Henan University of Chinese Medicine, Zhengzhou, 450046, China.
出版信息
Org Biomol Chem. 2022 May 18;20(19):3902-3906. doi: 10.1039/d2ob00557c.
PMID:35502883
Abstract
A photoexcited sulfenylation of C(sp)-H bonds in amides is developed for the synthesis of sulfenyl amides using thiosulfonates as a sulfur source. In the presence of easily available and inexpensive Na-eosin Y, TBHP and KCO, various sulfenyl amides can be obtained under the irradiation of blue light at room temperature.
摘要
发展了一种酰胺中 C(sp 3 )-H 键的光激发硫代磺酰化反应，使用硫代磺酸盐作为硫源合成了硫代酰胺。在易得且廉价的曙红 Y-Na、TBHP 和 KCO 的存在下，各种硫代酰胺可以在蓝光照射下于室温下得到。
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