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由硒化纳米晶体油墨制备的CuZnSn(S,Se)薄膜。

CuZnSn(S,Se) thin-films prepared from selenized nanocrystals ink.

作者信息

Aruna-Devi R, Latha M, Velumani S, Santos-Cruz J, Murali Banavoth, Chávez-Carvayar J-Á, Pulgarín-Agudelo F A, Vigil-Galán O

机构信息

Facultad de Química, Materiales-Energía, Universidad Autónoma de Querétaro 76010 Santiago de Querétaro Qro Mexico

Departamento de Ingeniería Eléctrica (SEES), CINVESTAV-IPN Av. IPN 2508 07360 San Pedro Zacatenco Mexico

出版信息

RSC Adv. 2019 Jun 11;9(32):18420-18428. doi: 10.1039/c9ra02669j. eCollection 2019 Jun 10.

DOI:10.1039/c9ra02669j
PMID:35515224
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9064833/
Abstract

For the first time, CZTS ink was formulated using low-temperature heating up synthesis of NCs. Besides, the influence of powder concentration on the properties of the films was examined. Subsequently, the CZTS films were annealed under a selenium (Se)/argon (Ar) atmosphere at different temperatures to enhance their properties. The influence of selenization temperature on the properties of CZTS films was examined in detail. Structural analysis showed a peak shift towards lower 2 values for CZTSSe films because of Se incorporation, resulting in larger lattice parameters for CZTSSe than CZTS. As the selenization temperature increases, an increment in the grain size was observed and the band gap was decreased from 1.52 to 1.05 eV. Hall Effect studies revealed a significant improvement in the mobility and carrier concentration with respect to selenization temperatures. Moreover, film selenized at 550 °C exhibited higher photoconductivity as compared to other films, indicating their potential application in the field of low-cost thin-film solar cells.

摘要

首次采用低温升温合成纳米晶的方法制备了CZTS墨水。此外，还研究了粉末浓度对薄膜性能的影响。随后，将CZTS薄膜在硒（Se）/氩（Ar）气氛中于不同温度下进行退火处理以改善其性能。详细研究了硒化温度对CZTS薄膜性能的影响。结构分析表明，由于硒的掺入，CZTSSe薄膜的峰值向较低的2值移动，导致CZTSSe的晶格参数比CZTS大。随着硒化温度的升高，观察到晶粒尺寸增加，带隙从1.52 eV降低到1.05 eV。霍尔效应研究表明，相对于硒化温度，迁移率和载流子浓度有显著改善。此外，与其他薄膜相比，在550℃硒化的薄膜表现出更高的光电导率，表明它们在低成本薄膜太阳能电池领域的潜在应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/436b/9064833/017906f5ce43/c9ra02669j-f8.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/436b/9064833/7ca743aa9af8/c9ra02669j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/436b/9064833/017906f5ce43/c9ra02669j-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/436b/9064833/e4d229dbc71b/c9ra02669j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/436b/9064833/07a281c9c91d/c9ra02669j-f2.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/436b/9064833/449d99390c3e/c9ra02669j-f5.jpg
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Nanoscale Res Lett. 2015 Dec;10(1):1045. doi: 10.1186/s11671-015-1045-6. Epub 2015 Aug 21.
3
One-step synthesis of high quality kesterite Cu2ZnSnS4 nanocrystals - a hydrothermal approach.
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Beilstein J Nanotechnol. 2014 Apr 9;5:438-46. doi: 10.3762/bjnano.5.51. eCollection 2014.
4
Crystallization behaviour of co-sputtered Cu₂ZnSnS₄ precursor prepared by sequential sulfurization processes.共溅射 Cu₂ZnSnS₄ 前驱体制备过程中硫的顺序硫化行为。
Nanotechnology. 2013 Mar 8;24(9):095706. doi: 10.1088/0957-4484/24/9/095706. Epub 2013 Feb 8.
5
A facile and general approach to polynary semiconductor nanocrystals via a modified two-phase method.一种通过改进的两相法制备多元半导体纳米晶的简便通用方法。
Nanotechnology. 2011 Jun 17;22(24):245605. doi: 10.1088/0957-4484/22/24/245605. Epub 2011 Apr 21.
6
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