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用于锂/钠离子电池和水系锌离子电池的钒酸钠纳米带的合成及电化学性能

Synthesis and electrochemical performance of NaVO nanobelts for Li/Na-ion batteries and aqueous zinc-ion batteries.

作者信息

Hu Fang, Xie Di, Cui Fuhan, Zhang Dongxu, Song Guihong

机构信息

School of Materials Science and Engineering, Shenyang University of Technology Shenyang 110870 China

出版信息

RSC Adv. 2019 Jul 2;9(36):20549-20556. doi: 10.1039/c9ra04339j. eCollection 2019 Jul 1.

Abstract

NaVO nanobelts were successfully synthesized for Li/Na-ion batteries and rechargeable aqueous zinc-ion batteries (ZIBs) by a facile hydrothermal reaction and subsequent thermal transformation. Compared to the electrochemical performance of LIBs and NIBs, NaVO nanobelt cathode materials in ZIBs have shown excellent electrochemical performance, including high specific capacity of 421 mA h g at 100 mA g and good cycle stability with a capacity retention of 94% over 500 cycles at 5 A g. The good diffusion coefficients and high surface capacity of NaVO nanobelts in ZIBs were in favor of fast Zn intercalation and long-term cycle stability.

摘要

通过简便的水热反应和随后的热转化,成功合成了用于锂/钠离子电池和可充电水系锌离子电池(ZIB)的钒酸钠纳米带。与锂离子电池和钠离子电池的电化学性能相比,ZIB中的钒酸钠纳米带正极材料表现出优异的电化学性能,包括在100 mA g下具有421 mA h g的高比容量,以及在5 A g下500次循环后容量保持率为94%的良好循环稳定性。ZIB中钒酸钠纳米带良好的扩散系数和高表面容量有利于锌的快速嵌入和长期循环稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1f17/9065744/f71a11fa47a3/c9ra04339j-f1.jpg

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