Genc Hayriye Nevin
Department of Science Education, A. K. Education Faculty, Necmettin Erbakan University Konya 42090 Turkey
RSC Adv. 2019 Jul 5;9(36):21063-21069. doi: 10.1039/c9ra03029h. eCollection 2019 Jul 1.
A highly enantioselective Michael addition reaction of anthrone with nitroalkenes by chiral tetraoxacalix[2]arene[2]triazine catalysts was investigated as a novel topic. The stereoselective conversion progressed smoothly by employing 10 mol% of the catalyst and afforded the corresponding Michael adducts with acceptable to high enantioselectivities (up to 97% ee) and very high yields (up to 96%).
研究了手性四氧杂杯[2]芳烃[2]三嗪催化剂催化蒽酮与硝基烯烃的高度对映选择性迈克尔加成反应这一新型课题。使用10 mol%的催化剂时，立体选择性转化顺利进行，得到相应的迈克尔加成产物，对映选择性良好至高（高达97% ee），产率非常高（高达96%）。
