Fan Chuan-Yan, Liu Jing-Xiao, Shi Fei, Ran Shuai, Chen Bin, Zhou Jing, Liu Su-Hua, Song Xin, Kang Jiahong
Key Laboratory of New Materials and Modification of Liaoning Province, School of Textile and Materials Engineering, Dalian Polytechnic University Dalian 116034 PR China
RSC Adv. 2019 Feb 15;9(10):5804-5814. doi: 10.1039/c8ra07626j. eCollection 2019 Feb 11.
Urchin-like Cs WO particles were synthesized using bacterial cellulose (BC) as a template by the hydrothermal method. The effects of the BC addition amount on the morphology, W content and transparent thermal insulation of Cs WO were studied. It has been confirmed that abnormal growth of Cs WO rods was greatly reduced after introduction of BC into the precursor solution. Moreover, introduction of BC into the precursor solution could significantly improve the transparent thermal insulation properties of the Cs WO film. In particular, when the BC amount was appropriate, the prepared Cs WO film exhibited better visible transparency, with the visible light transmittance ( ) more than 60%. In addition, the urchin-like particles could be transformed into small size nanorods after H heat-treatment, exhibiting excellent visible light transparency and thermal insulation performance. In particular, it has been proved that the 20BC-HT-Cs WO film exhibits excellent thermal insulation performance, and shows broad application prospects in the field of solar heat filters and energy-saving window glass.
以细菌纤维素(BC)为模板,采用水热法合成了海胆状Cs₂WO₄颗粒。研究了BC添加量对Cs₂WO₄的形貌、W含量和透明隔热性能的影响。已证实,将BC引入前驱体溶液后,Cs₂WO₄棒的异常生长大大减少。此外,将BC引入前驱体溶液可显著提高Cs₂WO₄薄膜的透明隔热性能。特别是,当BC用量适当时,制备的Cs₂WO₄薄膜具有更好的可见光透明度,可见光透射率( )超过60%。此外,海胆状颗粒在H热处理后可转化为小尺寸纳米棒,具有优异的可见光透明度和隔热性能。特别是,已证明20BC-HT-Cs₂WO₄薄膜具有优异的隔热性能,在太阳能热过滤器和节能窗玻璃领域具有广阔的应用前景。