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多元醇介导的细菌纤维素模板 ZnO 纳米粒子的合成。

Polyol mediated synthesis of ZnO nanoparticles templated by bacterial cellulose.

机构信息

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Key Laboratory of Textile Science & Technology (Ministry of Education), College of Materials Science and Engineering, Donghua University, Shanghai 201620, PR China.

出版信息

Carbohydr Polym. 2013 Feb 15;92(2):1953-9. doi: 10.1016/j.carbpol.2012.11.059. Epub 2012 Nov 29.

Abstract

Zinc oxide nanoparticles have been successfully synthesized through a facile polyol method using bacterial cellulose (BC) as a template. BC membrane was used as a host matrix to introduce quantitatively Zn(2+) ions and then as nanoreactors to fabricate ZnO nanoparticles by hydrolysis of zinc acetate in a polyol medium. The influence of the concentration of zinc acetate and hydrolytic time on the morphologies and size of ZnO nanoparticles were investigated. The results indicated that the uniform spherical ZnO nanoparticles were incorporated into BC fibers. The resulting nanocomposites show good mechanical properties and high photocatalytic activity in the degradation of methyl orange.

摘要

氧化锌纳米粒子已通过简便的多元醇法成功合成,使用细菌纤维素 (BC) 作为模板。BC 膜用作主基质以定量引入 Zn(2+)离子,然后作为纳米反应器,在多元醇介质中通过乙酸锌的水解来制备 ZnO 纳米粒子。研究了乙酸锌浓度和水解时间对 ZnO 纳米粒子形貌和尺寸的影响。结果表明,均匀的球形 ZnO 纳米粒子被掺入 BC 纤维中。所得纳米复合材料在降解甲基橙方面表现出良好的机械性能和高光催化活性。

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