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聚乙烯醇(PVA)与壳聚糖(CS)交联并结合嵌合二氧化硅纳米颗粒附着,以增强聚四氟乙烯(PTFE)平板膜的亲水性和抗菌性能。

PVA and CS cross-linking combined with chimeric SiO nanoparticle adhesion to enhance the hydrophilicity and antibacterial properties of PTFE flat membranes.

作者信息

Li Chengcai, Zhang Hang, Wang Feng, Zhu Hailin, Guo Yuhai, Chen Meiyu

机构信息

Zhejiang Provincial Key Laboratory of Fiber Materials and Manufacturing Technology, Zhejiang Sci-Tech University Hangzhou 310018 China

Zhejiang Kertice Hi-Tech Fluor-Material Co., LTD Huzhou 313000 People's Republic of China.

出版信息

RSC Adv. 2019 Jun 18;9(33):19205-19216. doi: 10.1039/c9ra02396h. eCollection 2019 Jun 14.

Abstract

Herein, a new hydrophilic and antibacterial polytetrafluoroethylene (PTFE) flat MF membrane was fabricated a low-cost and simple preparation method in which chitosan (CS) was crosslinked with poly(vinyl alcohol) (PVA) using epichlorohydrin (ECH) as a cross-linker followed by chimeric SiO nanoparticle adhesion. The surface of the modified membrane had decreased C and F contents, and a large number of hydrophilic groups appeared. The treated membrane had good hydrophilicity and antibacterial properties. Moreover, the PTFE-modified membrane had high separation efficiency and antifouling property for oil-in-water emulsions. Finally, the hydrophilic stability of the PTFE membrane was studied by subjecting it to continuous water rinsing and soaking in solutions of different pH values. The present study demonstrates that this modified membrane has potential practical applications in industrial wastewater recovery.

摘要

在此,通过一种低成本且简单的制备方法制备了一种新型的亲水性抗菌聚四氟乙烯(PTFE)平板微滤膜。该方法中,壳聚糖(CS)与聚乙烯醇(PVA)使用环氧氯丙烷(ECH)作为交联剂进行交联,随后进行嵌合SiO纳米颗粒附着。改性膜表面的C和F含量降低,并且出现了大量亲水性基团。处理后的膜具有良好的亲水性和抗菌性能。此外,PTFE改性膜对水包油乳液具有高分离效率和抗污染性能。最后,通过对PTFE膜进行连续水冲洗以及浸泡在不同pH值的溶液中,研究了其亲水性稳定性。本研究表明,这种改性膜在工业废水回收方面具有潜在的实际应用价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0cf4/9064884/245fe96656fb/c9ra02396h-f1.jpg

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