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用于环境应用的BiVO纳米颗粒的合成与表征。

Synthesis and characterization of BiVO nanoparticles for environmental applications.

作者信息

Ganeshbabu M, Kannan N, Venkatesh P Sundara, Paulraj G, Jeganathan K, MubarakAli D

机构信息

Nanomaterials Laboratory, Department of Physics, Sri S. Ramasamy Naidu Memorial College Sattur-626 203 Tamilnadu India

Centre for Nanoscience and Nanotechnology, Department of Physics, Bharathidasan University Tiruchirappalli-620 024 Tamilnadu India.

出版信息

RSC Adv. 2020 May 13;10(31):18315-18322. doi: 10.1039/d0ra01065k. eCollection 2020 May 10.

Abstract

In the present study, a chemical precipitation method is adopted to synthesize bismuth vanadate nanoparticles. The calcination temperature dependent photocatalytic and antibacterial activities of BiVO nanoparticles are examined. The structural analysis evidences the monoclinic phase of BiVO nanoparticles, where the grain size increases with calcination temperature. Interestingly, BiVO nanoparticles calcined at 400 °C exhibit superior photocatalytic behaviour against methylene blue dye ( = 0.02169 min) under natural solar irradiation, which exhibits good stability for up to three cycles. The evolution of antibacterial activity studies using a well diffusion assay suggest that the BiVO nanoparticles calcined at 400 °C can act as an effective growth inhibitor of pathogenic Gram-negative ( & ) and Gram-positive bacteria ().

摘要

在本研究中,采用化学沉淀法合成钒酸铋纳米颗粒。研究了煅烧温度对BiVO纳米颗粒光催化和抗菌活性的影响。结构分析证明了BiVO纳米颗粒的单斜晶相,其晶粒尺寸随煅烧温度的升高而增大。有趣的是,在400℃煅烧的BiVO纳米颗粒在自然太阳光照射下对亚甲基蓝染料表现出优异的光催化性能(k = 0.02169 min⁻¹),并且在三个循环内表现出良好的稳定性。使用平板扩散法进行的抗菌活性研究表明,在400℃煅烧的BiVO纳米颗粒可以作为致病性革兰氏阴性菌(大肠杆菌和肺炎克雷伯菌)和革兰氏阳性菌(金黄色葡萄球菌)的有效生长抑制剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbea/9053757/54d946c6114f/d0ra01065k-f1.jpg

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