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用于光学测温的含β-NaYF:Yb、Er纳米晶体的透明玻璃陶瓷的上转换

Upconversion of transparent glass ceramics containing β-NaYF:Yb, Er nanocrystals for optical thermometry.

作者信息

Li Xinyue, Yang Longyu, Zhu Yiwen, Zhong Jiasong, Chen Daqin

机构信息

College of Materials & Environmental Engineering, Hangzhou Dianzi University Hangzhou 310018 P. R. China

College of Physics and Energy, Fujian Normal University Fuzhou 350117 P. R. China

出版信息

RSC Adv. 2019 Mar 11;9(14):7948-7954. doi: 10.1039/c9ra01088b. eCollection 2019 Mar 6.

Abstract

β-NaYF nanocrystal embedded glass ceramics were fabricated by a melt-quenching method with subsequent heat-treatment. Structural characterizations and spectrographic techniques were performed to verify the successful precipitation of β-NaYF nanocrystals and partition of dopants. Upon excitation of 980 nm, bright green upconversion emission could be achieved in Yb, Er codoped β-NaYF nanocrystal embedded glass ceramics. Furthermore, the temperature-dependent upconversion behaviour based on thermally coupled energy levels was also examined in the range of 300-773 K with the maximum relative sensitivity of 1.24% K at 300 K. Accordingly, it has been proved to be a promising candidate for application in optical thermometry.

摘要

通过熔融淬火法并随后进行热处理制备了β-NaYF纳米晶嵌入的玻璃陶瓷。采用结构表征和光谱技术来验证β-NaYF纳米晶的成功析出以及掺杂剂的分布。在980 nm激发下,Yb、Er共掺杂的β-NaYF纳米晶嵌入玻璃陶瓷中可实现明亮的绿色上转换发射。此外,还在300-773 K范围内研究了基于热耦合能级的温度依赖性上转换行为,在300 K时最大相对灵敏度为1.24% K。因此,它已被证明是光学测温应用中有前景的候选材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/322a/9061238/532a6346f364/c9ra01088b-f1.jpg

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