Considering single-atom catalysts as photocatalysts from synthesis to application.

With the ever-increased greenhouse effect and energy crisis, developing novel photocatalysts to realize high-efficient solar-driven chemicals/fuel production is of great scientific and practical significance. Recently, single-atom photocatalysts (SAPs) are promising catalysts with maximized metal dispersion and tuneable coordination environments. SAPs exhibit boosted photocatalytic performance by enhancing optical response, facilitating charge carrier transfer behaviors or directly manipulating surface reaction processes. In this regard, this article systematically reviews the state-of-the-art progress in the development and application of SAPs, especially the mechanism and performance of SAPs on various reaction processes. Some future challenges and potential research directions over SAPs are outlined at the final stage.