Dong Yanjie, Sang Dashen, He Chengdong, Sheng Xinfeng, Lei Longwen
Anhui Provincial Laboratory of Optoelectronic and Magnetism Functional Materials, College of Chemistry and Chemical Engineering, Anqing Normal University Anqing 246011 People's Republic of China
RSC Adv. 2019 Sep 16;9(50):29015-29022. doi: 10.1039/c9ra05251h. eCollection 2019 Sep 13.
Mxene has been widely used as a sorbent to remove heavy metal ions from sewage due to its unique two-dimensional layered structure and abundant oxygen-containing groups. However, Mxene has a relatively limited adsorption capacity for metal ions possibly due to the limited adsorption active sites. Herein, we reported novel Mxene/alginate composites for lead and copper ion removal from wastewater. The Mxene/alginate composites prepared in this study not only enhance the chelation ability of the lead and copper ions, but also accelerate the ion transport efficiency. The combined advantages of high adsorption capacity and short equilibrium time enable the Mxene/alginate composites to achieve the maximum adsorption capacity for Pb and Cu at 382.7 and 87.6 mg g, respectively, and reach the adsorption equilibrium in 15 min. We believe that the composites developed in this study can open a new avenue for designing high adsorption capacity and high efficiency adsorbents.
由于其独特的二维层状结构和丰富的含氧基团,MXene已被广泛用作吸附剂从污水中去除重金属离子。然而,MXene对金属离子的吸附容量相对有限,这可能是由于吸附活性位点有限所致。在此,我们报道了用于从废水中去除铅和铜离子的新型MXene/藻酸盐复合材料。本研究制备的MXene/藻酸盐复合材料不仅增强了对铅和铜离子的螯合能力,还提高了离子传输效率。高吸附容量和短平衡时间的综合优势使MXene/藻酸盐复合材料对Pb和Cu的最大吸附容量分别达到382.7和87.6 mg/g,并在15分钟内达到吸附平衡。我们相信,本研究开发的复合材料可为设计高吸附容量和高效率的吸附剂开辟一条新途径。