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使用偶氮苯衍生物对基于卵磷脂的反向蠕虫状胶束体系进行光致粘度控制。

Photoinduced viscosity control of lecithin-based reverse wormlike micellar systems using azobenzene derivatives.

作者信息

Akamatsu Masaaki, Shiina Mayu, Shrestha Rekha Goswami, Sakai Kenichi, Abe Masahiko, Sakai Hideki

机构信息

Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science 2641 Yamazaki Noda Chiba 278-8510 Japan.

Research Institute for Science and Technology, Tokyo University of Science 2641 Yamazaki Noda Chiba 278-8510 Japan.

出版信息

RSC Adv. 2018 Jun 29;8(42):23742-23747. doi: 10.1039/c8ra04690e. eCollection 2018 Jun 27.

DOI:10.1039/c8ra04690e
PMID:35540289
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9081822/
Abstract

This report describes the controlled viscosity changes of photoresponsive reverse wormlike micellar systems formed by soybean lecithin (SoyPC), d-ribose, and azobenzene derivatives in decane. UV light irradiation produces a significant (150-fold) decrease in solution viscosity by triggering a structural transformation of the wormlike micelles. Subsequent visible light irradiation leads to recovery of the initial micellar structure and elevated solution viscoelasticity. This dramatic, reversible variation in solution viscosity by light irradiation can be applied to cosmetics, personal care products, and device components.

摘要

本报告描述了由大豆卵磷脂（SoyPC）、d-核糖和偶氮苯衍生物在癸烷中形成的光响应性反向蠕虫状胶束体系的可控粘度变化。紫外线照射通过引发蠕虫状胶束的结构转变，使溶液粘度显著降低（150倍）。随后的可见光照射导致初始胶束结构恢复，溶液粘弹性升高。这种通过光照射使溶液粘度发生的显著、可逆变化可应用于化妆品、个人护理产品和器件组件。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/95831b13b444/c8ra04690e-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/6aa291c131ab/c8ra04690e-s1.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/9a88ab49c0e8/c8ra04690e-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/c3e35396d115/c8ra04690e-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/764de66938e2/c8ra04690e-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/95831b13b444/c8ra04690e-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/6aa291c131ab/c8ra04690e-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/be327ff9ea26/c8ra04690e-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/9a88ab49c0e8/c8ra04690e-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/c3e35396d115/c8ra04690e-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/764de66938e2/c8ra04690e-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/9081822/95831b13b444/c8ra04690e-f5.jpg

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本文引用的文献

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Soft Matter. 2007 Jul 17;3(8):956-970. doi: 10.1039/b705775j.
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A light-responsive organofluid based on reverse worm-like micelles formed from an equi-charged, mixed, anionic gemini surfactant with an azobenzene spacer and a cationic conventional surfactant.一种基于反向蠕虫状胶束的光响应型有机流体，由等电荷、混合的、阴离子双子表面活性剂与偶氮苯间隔基和阳离子常规表面活性剂形成。
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Micelle structure in a photoresponsive surfactant with and without solubilized ethylbenzene from small-angle neutron scattering.
基于小角中子散射研究含与不含增溶乙苯的光响应表面活性剂中的胶束结构
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Light-responsive threadlike micelles as drag reducing fluids with enhanced heat-transfer capabilities.具有增强传热能力的光响应线状胶束减阻流体。
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